ArticleACS applied materials & interfaces2021
Improving the Robustness of Organic Semiconductors through Hydrogen Bonding.
Article in ACS applied materials & interfaces, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Boosting the Dopant Accommodation in Charge-Transfer Supramolecular Electrets Using Carbohydrate Block Copolymers in Phototransistor Memory.ACS omega · 2026Article
- Tuning Conjugation and Charge Transport in Supramolecular Semiconductors via Hydrogen-Bonding Position.Small science · 2026Article
- Hydrogen-Bond-Directed Supramolecular Organic Semiconductor Thin Films Realized via Thermal Precursor Approach.Angewandte Chemie (International ed. in English) · 2025Article
- Revealing the Role of Spacer Length and Methoxy Substitution of Dipodal Indolocarbazole-based SAMs on the Performance of Inverted Perovskite Solar Cells.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)Molecules (Basel, Switzerland) · 2024Article
- On-Surface Synthesis of a Radical 2D Supramolecular Organic Framework.Journal of the American Chemical Society · 2024Article
- Structure-property relationships in dicyanopyrazinoquinoxalines and their hydrogen-bonding-capable dihydropyrazinoquinoxalinedione derivatives.Beilstein journal of organic chemistry · 2024Article
- Two-Dimensional Self-Assembly Driven by Intermolecular Hydrogen Bonding in Benzodi-7-azaindole Molecules on Au(111).The journal of physical chemistry. C, Nanomaterials and interfaces · 2023Article
- 2D-Self-Assembled Organic Materials in Undoped Hole Transport Bilayers for Efficient Inverted Perovskite Solar Cells.ACS applied materials & interfaces · 2023Article
- Crystal Structures of Lignocellulosic Furfuryl Biobased Polydiacetylenes with Hydrogen-Bond Networks: Influencing the Direction of Solid-State Polymerization through Modification of the Spacer Length.Crystal growth & design · 2022Article
- Optical Study of Solvatochromic Isocyanoaminoanthracene Dyes and 1,5-Diaminoanthracene.International journal of molecular sciences · 2022Article
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Authors and funding
8 authors.
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Abstract
Molecular organization plays an essential role in organic semiconductors since it determines the extent of intermolecular interactions that govern the charge transport present in all electronic applications. The benefits of hydrogen bond-directed self-assembly on charge transport properties are demonstrated by comparing two analogous pyrrole-based, fused heptacyclic molecules. The rationally designed synthesis of these materials allows for inducing or preventing hydrogen bonding. Strategically located hydrogen bond donor and acceptor sites control the solid-state arrangement, favoring the supramolecular expansion of the π-conjugated surface and the subsequent π-stacking as proved by X-ray diffraction and computational calculations. The consistency observed for the performance of organic field-effect transistors and the morphology of the organic thin films corroborate that higher stability and thermal robustness are achieved in the hydrogen-bonded material.
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