ArticleJournal of synchrotron radiation2020
Soft X-ray absorption spectroscopy in the low-energy region explored using an argon gas window.
Article in Journal of synchrotron radiation, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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Abstract
The soft X-ray region below 200 eV is important for investigating chemical and biological phenomena since it covers K-edges of Li and B and L-edges of Si, P, S and Cl. Helium gas is generally used as the soft X-ray transmission window for soft X-ray absorption spectroscopy (XAS) under atmospheric conditions. However, the helium gas window cannot be applied to XAS in the low-energy region since transmitted soft X-rays mostly consist of high-order X-rays due to the low transmission of first-order X-rays. In this study, the argon gas window is proposed as a new soft X-ray transmission window in the low-energy region. High-order X-rays are removed by the absorption of the Ar L-edge (240 eV), and first-order X-rays become the major contribution of transmitted soft X-rays in the low-energy region. Under atmospheric argon conditions, the double-excitation Rydberg series of helium gas (60 eV), Si L-edge XAS of an Si
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