Evidence map›Paper›PMID 33562577›Full record

ArticleMaterials (Basel, Switzerland)2021

Resins for Frontal Photopolymerization: Combining Depth-Cure and Tunable Mechanical Properties.

Catharina Ebner, Julia Mitterer, Joamin Gonzalez-Gutierrez, Gisbert Rieß, Wolfgang Kern

Abstract read
In one paragraph

Article in Materials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Catharina EbnerDepartment of Polymer Engineering and Science, Chair in Chemistry of Polymeric Materials, University of Leoben, 8700 Leoben, Austria.
Julia MittererDepartment of Polymer Engineering and Science, Chair in Chemistry of Polymeric Materials, University of Leoben, 8700 Leoben, Austria.
Joamin Gonzalez-GutierrezDepartment of Polymer Engineering and Science, Chair of Polymer Processing, University of Leoben, 8700 Leoben, Austria.ORCID 0000-0003-4737-9823
Gisbert RießDepartment of Polymer Engineering and Science, Chair in Chemistry of Polymeric Materials, University of Leoben, 8700 Leoben, Austria.
Wolfgang KernDepartment of Polymer Engineering and Science, Chair in Chemistry of Polymeric Materials, University of Leoben, 8700 Leoben, Austria.ORCID 0000-0002-7962-9199

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Photopolymerization has undergone significant development in recent years. It enables fast and easy processing of materials with customized properties and allows precise printing of complex surface geometries. Nevertheless, photopolymerization is mainly applied to cure thin films since the low curing depth limits the fast production of large volumes. Frontal photopolymerization (FPP) is suitable to overcome these limitations so that curing of centimeter-thick (meth)acrylic layers can be accomplished within minutes by light induction only. Prerequisites, however, are the low optical density of the resin and bleaching ability of the photoinitiator. To date, tailored FPP-resins are not commercially available. This study discusses the potential of long-chain polyether dimethacrylates, offering high-temperature resistance and low optical density, as crosslinkers in photobleaching resins and investigates the mechanical properties of photofrontally-cured copolymers. Characteristics ranging from ductile to hard and brittle are observed in tensile tests, demonstrating that deep curing and versatile material properties are achieved with FPP. Analyzed components display uniform polymerization over a depth of four centimeters in Fourier transform infrared spectroscopy and swelling tests.

Indexed as

frontal photopolymerization(meth) acrylate polymersphotobleachingphotofrontal polymerizationpolyolTPO-L

Identifiers

PMID33562577
PMCPMC7914558

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.