Evidence map›Paper›PMID 33555663›Full record

ArticleChemphyschem : a European journal of chemical physics and physical chemistry2021

The Gauche Effect in XCH

Daniela Rodrigues Silva, Lucas de Azevedo Santos, Trevor A Hamlin, Célia Fonseca Guerra, Matheus P Freitas, F Matthias Bickelhaupt

Abstract read
In one paragraph

Article in Chemphyschem : a European journal of chemical physics and physical chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.

0numbers the graph read from it
0cells of the map it votes in
14citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

14 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Difluorinated Cyclohexanes: Energetics and Intra- and Intermolecular Interactions.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025
    Article
  5. Article
  6. Exploring the Helical Structure of Ethylene Oxides: Beyond Steric and Related Effects.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025
    Article
  7. Review
  8. Bis(2-chloro-Acta crystallographica. Section E, Crystallographic communications · 2024
    Article
  9. Discovery of internal rotation and conformers of 1,2-dichloroethane: the dawn of the concept of conformation.Proceedings of the Japan Academy. Series B, Physical and biological sciences · 2024
    Article
  10. Review
  11. 3-Chloro-IUCrData · 2023
    Article
  12. Dipolar repulsion in α-halocarbonyl compounds revisited.Physical chemistry chemical physics : PCCP · 2021
    Article
  13. Steric effectsRSC advances · 2021
    Article
  14. The Gauche Effect in XCHChemphyschem : a European journal of chemical physics and physical chemistry · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Daniela Rodrigues SilvaDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID 0000-0002-8191-7130
Lucas de Azevedo SantosDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID 0000-0002-4040-1728
Trevor A HamlinDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID 0000-0002-5128-1004
Célia Fonseca GuerraDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID 0000-0002-2973-5321
Matheus P FreitasDepartamento de Química, Instituto de Ciências Naturais, Universidade Federal de Lavras, 37200-900, Lavras-MG, Brazil.ORCID 0000-0002-7492-1801
F Matthias BickelhauptDepartment of Theoretical Chemistry, Amsterdam Institute of Molecular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, 1081 HV, Amsterdam (The, Netherlands.ORCID 0000-0003-4655-7747

Funding

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de Minas Gerais (FAPEMIG)Netherlands Organization for Scientific Research (NWO)
6 · The paper itself

Abstract

We have quantum chemically investigated the rotational isomerism of 1,2-dihaloethanes XCH

Indexed as

activation strain modelbond theoryconformational analysisenergy decomposition analysisgauche effect

Identifiers

PMID33555663
PMCPMC8048458

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.