Evidence map›Paper›PMID 33553108›Full record

ReviewFrontiers in chemistry2020

Recent Approaches for Chemical Speciation and Analysis by Electrospray Ionization (ESI) Mass Spectrometry.

Serena Indelicato, David Bongiorno, Leopoldo Ceraulo

Abstract readReview
In one paragraph

Review in Frontiers in chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. UntreatedMolecules (Basel, Switzerland) · 2023
    Article
  5. Article
  6. Article
  7. Hydroxyl transferFrontiers in chemistry · 2022
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Serena IndelicatoDipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche (STEBICEF), Università degli studi di Palermo, Palermo, Italy.
David BongiornoDipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche (STEBICEF), Università degli studi di Palermo, Palermo, Italy.
Leopoldo CerauloDipartimento di Scienze e Tecnologie Biologiche Chimiche e Farmaceutiche (STEBICEF), Università degli studi di Palermo, Palermo, Italy.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

In recent years, the chemical speciation of several species has been increasingly monitored and investigated, employing electrospray ionization mass spectrometry (ESI-MS). This soft ionization technique gently desolvates weak metal-ligand complexes, taking them in the high vacuum sectors of mass spectrometric instrumentation. It is, thus, possible to collect information on their structure, energetics, and fragmentation pathways. For this reason, this technique is frequently chosen in a synergistic approach to investigate competitive ligand exchange-adsorption otherwise analyzed by cathodic stripping voltammetry (CLE-ACSV). ESI-MS analyses require a careful experimental design as measurement may face instrumental artifacts such as ESI adduct formation, fragmentation, and sometimes reduction reactions. Furthermore, ESI source differences of ionization efficiencies among the detected species can be misleading. In this mini-review are collected and critically reported the most recent approaches adopted to mitigate or eliminate these limitations and to show the potential of this analytical technique.

Indexed as

electrospray ionizationmass spectrometrymetallomicsmetals speciationspeciation analysis

Identifiers

PMID33553108
PMCPMC7855954

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.