ArticleProceedings of the National Academy of Sciences of the United States of America2021
Geometrical manipulation of complex supramolecular tessellations by hierarchical assembly of amphiphilic platinum(II) complexes.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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8 citing papers in PubMed.
- Supramolecular assembly strategy of multinuclear platinum(ii) complexes for proof-of-concept detection and extraction of perfluorohexanoic acid.Chemical science · 2026Article
- Controlled supramolecular assemblies of luminescent tridentate cyclometalated alkynylgold(III) amphiphiles in aqueous media.Beilstein journal of organic chemistry · 2026Article
- Thermoresponsive Platinum(II) 2,6-Di(pyrid-2-yl)pyrazine Complexes with Unusual Aggregation Behavior upon Heating.Journal of the American Chemical Society · 2025Article
- Exploring diverse supramolecular tessellation through hierarchical assemblies of nonalternant nanographene.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(ii) terpyridine complex through competitive complex formation.Chemical science · 2024Article
- Controlling supramolecular copolymerization of alkynylplatinum(ii) terpyridine complexes: from isodesmic to cooperative mechanisms.Nanoscale advances · 2024Article
- Metal-organic cycle-based multistage assemblies.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Anthracene-induced formation of highly twisted metallacycle and its crystal structure and tunable assembly behaviors.Proceedings of the National Academy of Sciences of the United States of America · 2021Article
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5 authors.
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Abstract
Here we report complex supramolecular tessellations achieved by the directed self-assembly of amphiphilic platinum(II) complexes. Despite the twofold symmetry, these geometrically simple molecules exhibit complicated structural hierarchy in a columnar manner. A possible key to such an order increase is the topological transition into circular trimers, which are noncovalently interlocked by metal···metal and π-π interactions, thereby allowing for cofacial stacking in a prismatic assembly. Another key to success is to use the immiscibility of the tailored hydrophobic and hydrophilic sidechains. Their phase separation leads to the formation of columnar crystalline nanostructures homogeneously oriented on the substrate, featuring an unusual geometry analogous to a rhombitrihexagonal Archimedean tiling. Furthermore, symmetry lowering of regular motifs by design results in an orthorhombic lattice obtained by the coassembly of two different platinum(II) amphiphiles. These findings illustrate the potentials of supramolecular engineering in creating complex self-assembled architectures of soft materials.
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