ArticleACS applied materials & interfaces2021
Smectic Liquid Crystalline Polymer Membranes with Aligned Nanopores in an Anisotropic Scaffold.
Article in ACS applied materials & interfaces, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Hydrogen-Bonded Structures of Water Molecules in Hydroxy-Functionalized Nanochannels of Columnar Liquid Crystalline Nanostructured Membranes Studied by Soft X-ray Emission Spectroscopy.The journal of physical chemistry letters · 2024Article
- Photo-responsive nanoporous liquid crystal polymer films for selective dye adsorption.RSC advances · 2024Article
- Hydrogen-Bonded Supramolecular Liquid Crystal Polymers: Smart Materials with Stimuli-Responsive, Self-Healing, and Recyclable Properties.Chemical reviews · 2022Review
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Authors and funding
6 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Bottom-up methods for the fabrication of nanoporous polymer membranes have numerous advantages. However, it remains challenging to fabricate nanoporous membranes that are mechanically robust and have aligned pores, that is, with a low tortuosity. Here, a mechanically robust thin-film composite membrane was fabricated consisting of a two-dimensional (2D) porous smectic liquid crystalline polymer network inside an anisotropic, microporous polymer scaffold. The polymer scaffold allows for relatively straightforward planar alignment of the smectic liquid crystalline mixture, which consisted of a diacrylate cross-linker and a dimer forming benzoic acid-based monoacrylate. Polymerized samples displayed a smectic A (SmA) phase, which formed the eventual 2D porous channels after base treatment. The aligned 2D nanoporous membranes showed a high rejection of anionic solutes bigger than 322 g/mol. Cleaning and reusability of the system were demonstrated by intentionally fouling the porous channels with a cationic dye and subsequently cleaning the membrane with an acidic solution. After cleaning, the membrane properties were unaffected; this, combined with numerous pressurizing cycles, demonstrated reusability of the system.
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