ArticleJournal of the American Chemical Society2021
Soluble/MOF-Supported Palladium Single Atoms Catalyze the Ligand-, Additive-, and Solvent-Free Aerobic Oxidation of Benzyl Alcohols to Benzoic Acids.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 24 papers.
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Who cites it
24 citing papers in PubMed, 118 citations in OpenAlex.
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- Structure-activity relationships in the development of single atom catalysts for sustainable organic transformations.Nanoscale advances · 2025Review
- Exploration of Regulation of Alcohol Dehydrogenation Reaction of Dibenzimidazole-Based Ruthenium Complexes.Molecules (Basel, Switzerland) · 2025Article
- Bioinspired metal-organic frameworks for aqueous environment decontamination: from laboratory scale to real-world technologies.Chemical communications (Cambridge, England) · 2024Review
- Design of Multivariate Biological Metal-Organic Frameworks: Toward Mimicking Active Sites of Enzymes.Inorganic chemistry · 2024Article
- Soluble individual metal atoms and ultrasmall clusters catalyze key synthetic steps of a natural product synthesis.Communications chemistry · 2024Article
- Selective cycloaddition of ethylene oxide to CODalton transactions (Cambridge, England : 2003) · 2023Article
- Single-Atom Platinum Catalyst for Efficient COMolecules (Basel, Switzerland) · 2023Article
- Selective CONature communications · 2023Article
- Pd-Coordinated Salinidol-Modified Mixed MOF: An Excellent Active Center for Efficient Nitroarenes Reduction and Selective Oxidation of Alcohols.ACS omega · 2023Article
- Exploring the Role of Amino Acid-Derived Multivariate Metal-Organic Frameworks as Catalysts in Hemiketalization Reactions.Inorganic chemistry · 2023Article
- MOF-Triggered Synthesis of Subnanometer AgJournal of the American Chemical Society · 2023Article
- Recent Advances on Transition-Metal-Based Layered Double Hydroxides Nanosheets for Electrocatalytic Energy Conversion.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Parts-Per-Million of Soluble PdThe Journal of organic chemistry · 2023Article
- Role of molecular modelling in the development of metal-organic framework for gas adsorption applications.Journal of chemical sciences (Bangalore, India) · 2023Review
- Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction.Inorganic chemistry · 2022Article
- Metal-Organic Frameworks as Unique Platforms to Gain Insight of σ-Hole Interactions for the Removal of Organic Dyes from Aquatic Ecosystems.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
Corrections and comments
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Authors and funding
13 authors at 5 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal single-atom catalysts (SACs) promise great rewards in terms of metal atom efficiency. However, the requirement of particular conditions and supports for their synthesis, together with the need of solvents and additives for catalytic implementation, often precludes their use under industrially viable conditions. Here, we show that palladium single atoms are spontaneously formed after dissolving tiny amounts of palladium salts in neat benzyl alcohols, to catalyze their direct aerobic oxidation to benzoic acids without ligands, additives, or solvents. With this result in hand, the gram-scale preparation and stabilization of Pd SACs within the functional channels of a novel methyl-cysteine-based metal-organic framework (MOF) was accomplished, to give a robust and crystalline solid catalyst fully characterized with the help of single-crystal X-ray diffraction (SCXRD). These results illustrate the advantages of metal speciation in ligand-free homogeneous organic reactions and the translation into solid catalysts for potential industrial implementation.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.