ArticleAngewandte Chemie (International ed. in English)2021
Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways*.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
15 citing papers in PubMed, 81 citations in OpenAlex.
- Two-Step Synthesis of a Chiral Fluorinated Alcohol With Silica-Supported Enzyme RrADH in Batch and Continuous Flow Mode.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Hydrogen Peroxide Producing Titania-Silica Supraparticles as Tailorable Photocatalysts for Flow Chemistry Reactions in Microfluidic Reactors.Chem & bio engineering · 2025Article
- Article
- Towards the rate limit of heterologous biotechnological reactions in recombinant cyanobacteria.Biotechnology for biofuels and bioproducts · 2023Article
- Light-driven biocatalytic oxidation.Chemical science · 2022Review
- Rapid and Replaceable Luminescent Coating for Silicon-Based Microreactors Enabling Energy-Efficient Solar Photochemistry.ACS sustainable chemistry & engineering · 2022Article
- A Biocatalytic Platform for the Synthesis of Enantiopure Propargylic Alcohols and Amines.Organic letters · 2022Article
- Red edge effect and chromoselective photocatalysis with amorphous covalent triazine-based frameworks.Nature communications · 2022Article
- Synthesis of Enantiopure Sulfoxides by Concurrent Photocatalytic Oxidation and Biocatalytic Reduction.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2022Article
- Synthesis of Enantiopure Sulfoxides by Concurrent Photocatalytic Oxidation and Biocatalytic Reduction.Angewandte Chemie (International ed. in English) · 2022Article
- A Peroxygenase-Alcohol Dehydrogenase Cascade Reaction to Transform Ethylbenzene Derivatives into Enantioenriched Phenylethanols.Chembiochem : a European journal of chemical biology · 2022Article
- Controlling Chemoselectivity of Catalytic Hydroboration with Light.Angewandte Chemie (International ed. in English) · 2022Article
- Chromoselective Synthesis of Sulfonyl Chlorides and Sulfonamides with Potassium Poly(heptazine imide) Photocatalyst.Angewandte Chemie (International ed. in English) · 2021Article
- Chromoselective Photocatalysis Enables Stereocomplementary Biocatalytic Pathways*.Angewandte Chemie (International ed. in English) · 2021Article
- Emerging concepts in photocatalytic organic synthesis.iScience · 2021Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
12 authors at 5 institutions in 4 countries.
Funding
Abstract
Controlling the selectivity of a chemical reaction with external stimuli is common in thermal processes, but rare in visible-light photocatalysis. Here we show that the redox potential of a carbon nitride photocatalyst (CN-OA-m) can be tuned by changing the irradiation wavelength to generate electron holes with different oxidation potentials. This tuning was the key to realizing photo-chemo-enzymatic cascades that give either the (S)- or the (R)-enantiomer of phenylethanol. In combination with an unspecific peroxygenase from Agrocybe aegerita, green light irradiation of CN-OA-m led to the enantioselective hydroxylation of ethylbenzene to (R)-1-phenylethanol (99 % ee). In contrast, blue light irradiation triggered the photocatalytic oxidation of ethylbenzene to acetophenone, which in turn was enantioselectively reduced with an alcohol dehydrogenase from Rhodococcus ruber to form (S)-1-phenylethanol (93 % ee).
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.