ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- Hydrogen atom abstraction by a high spin [FeChem · 2023Article
- Isostructural bridging diferrous chalcogenide cores [FeChemical science · 2023Article
- Between imide, imidyl and nitrene - an imido iron complex in two oxidation states.Chemical science · 2022Article
- A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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4 authors.
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Abstract
A [Fe-S-Fe] subunit with a single sulfide bridging two low-coordinate iron ions is the supposed active site of the iron-molybdenum co-factor (FeMoco) of nitrogenase. Here we report a dinuclear monosulfido bridged diiron(II) complex with a similar complex geometry that can be oxidized stepwise to diiron(II/III) and diiron(III/III) complexes while retaining the [Fe-S-Fe] core. The series of complexes has been characterized crystallographically, and electronic structures have been studied using, inter alia,
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