Synthesis of Chiral Helic[1]triptycene[3]arenes and Their Enantioselective Recognition Towards Chiral Guests Containing Aminoindan Groups.

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In one paragraph

Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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1citing papers in PubMed

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1 · What the graph read from it

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3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Chiral Nanocluster Complexes Formed by Host-Guest Interaction between Enantiomeric 2,6-Helic[6]arenes and Silver Cluster AgMolecules (Basel, Switzerland) · 2022
Article

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5 · Who and what money

Authors and funding

3 authors.

Jing LiBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Ying HanBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.

Chuan-Feng ChenBeijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.ORCID 0000-0002-4347-1406

Funding

the National Natural Science Foundation of China 21772205the National Natural Science Foundation of China 22031010the National Natural Science Foundation of China 91856117

6 · The paper itself

Abstract

Starting from the enantiopure precursors, a pair of chiral macrocyclic arenes named helic[1]triptycene[3]arenes were conveniently synthesized. The circular dichroism (CD) spectra of the enantiomeric macrocyclic arenes exhibited mirror images, and the X-ray single crystal structures confirmed their absolute conformations as well. Moreover, the macrocyclic arenes showed strong complexation with secondary ammonium and primary ammonium salts containing aminoindan groups. In particular, the chiral macrocyclic arenes exhibited enantioselective recognition ability towards the chiral secondary ammonium salts containing aminoindan groups with an enantioselective ratio up to 3.89.

Indexed as

StereoisomerismAmmonium CompoundsAnthracenesCircular DichroismIndansAmmonium CompoundsAnthracenesindanIndanstriptyceneammonium saltsenantioselective recognitionhelic[1]triptycene[3]arenemacrocyclic arene

Identifiers

PMID33498575

DOI10.3390/molecules26030536

PMCPMC7864338

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