Evidence map›Paper›PMID 33497500›Full record

ArticleAngewandte Chemie (International ed. in English)2021

Probing Physical Oxidation State by Resonant X-ray Emission Spectroscopy: Applications to Iron Model Complexes and Nitrogenase.

Rebeca G Castillo, Anselm W Hahn, Benjamin E Van Kuiken, Justin T Henthorn, Jeremy McGale, Serena DeBeer

Open access · hybridAbstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.

0numbers the graph read from it
0cells of the map it votes in
25citing papers in PubMed
8.5field-weighted citation impact, top 2% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

25 citing papers in PubMed, 41 citations in OpenAlex.

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  6. Operando Characterization of Fe in Doped NiJournal of the American Chemical Society · 2025
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  10. Determination of Uranium Central-Field Covalency with 3Journal of the American Chemical Society · 2024
    Article
  11. Article
  12. X-ray absorption and emission spectroscopy of NDalton transactions (Cambridge, England : 2003) · 2024
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  13. Article
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  16. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 1 country.

Rebeca G CastilloDepartment of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Anselm W HahnDepartment of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Benjamin E Van KuikenEuropean XFEL, Holzkoppel 4, 22869, Schenefeld, Germany.
Justin T HenthornDepartment of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Jeremy McGaleDepartment of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
Serena DeBeerDepartment of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.ORCID 0000-0002-5196-3400
Max Planck Institute for Chemical Energy Conversion · DEEuropean X-Ray Free-Electron Laser · DE

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The ability of resonant X-ray emission spectroscopy (XES) to recover physical oxidation state information, which may often be ambiguous in conventional X-ray spectroscopy, is demonstrated. By combining Kβ XES with resonant excitation in the XAS pre-edge region, resonant Kβ XES (or 1s3p RXES) data are obtained, which probe the 3d

Indexed as

Iron CompoundsMolecular ConformationNitrogenaseOxidation-ReductionSpectrometry, X-Ray EmissionIron CompoundsNitrogenaseiron complexesmolybdenumnitrogenaseoxidation statesvalence-to-core X-ray emission spectroscopy

Identifiers

PMID33497500
PMCPMC8252016
OpenAlexW3122334046

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.