ArticleJournal of the American Chemical Society2021
Fluoroarene Separations in Metal-Organic Frameworks with Two Proximal Mg
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Shape-Recognition in an Al-MOF Enables High CAdvanced materials (Deerfield Beach, Fla.) · 2026Article
- Dual engineering of thermodynamics and kinetics in covalent organic frameworks for separation.Nature communications · 2026Article
- Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal-Organic Frameworks.Nano-micro letters · 2025Review
- Temperature-dependent molecular sieving of fluorinated propane/propylene mixtures by a flexible-robust metal-organic framework.Science advances · 2024Article
- Kinetic Trapping of Photoluminescent Frameworks During High-Concentration Synthesis of Non-Emissive Metal-Organic Frameworks.Chemistry of materials : a publication of the American Chemical Society · 2023Article
- Simplifying the Synthesis of Metal-Organic Frameworks.Accounts of materials research · 2023Article
- Handling fluorinated gases as solid reagents using metal-organic frameworks.Science (New York, N.Y.) · 2023Article
- Evaluating Solvothermal and Mechanochemical Routes towards the Metal-Organic Framework MgCrystEngComm · 2022Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Fluoroarenes are widely used in medicinal, agricultural, and materials chemistry, and yet their production remains a critical challenge in organic synthesis. Indeed, the nearly identical physical properties of these vital building blocks hinders their purification by traditional methods, such as flash chromatography or distillation. As a result, the Balz-Schiemann reaction is currently employed to prepare fluoroarenes instead of more atom-economical C-H fluorination reactions, which produce inseparable mixtures of regioisomers. Herein, we propose an alternative solution to this problem: the purification of mixtures of fluoroarenes using metal-organic frameworks (MOFs). Specifically, we demonstrate that controlling the interaction of fluoroarenes with adjacent coordinatively unsaturated Mg
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Registered trials
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