ArticleACS macro letters2021
Dual-Cationic Poly(ionic liquid)s Carrying 1,2,4-Triazolium and Imidazolium Moieties: Synthesis and Formation of a Single-Component Porous Membrane.
Article in ACS macro letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Application of Novel Triazolium-Containing Hydrogels to Cotton Fabrics: Evaluation of Their Flame Retardancy and Antibacterial Properties.ACS omega · 2025Article
- Thermal Responsiveness of 1,2,4-Triazolium-Based Poly(ionic liquid)s and Their Applications in Dye Extraction and Smart Switch.ACS applied polymer materials · 2024Article
- A novel magnetic FSM-16 supported ionic liquid/Pd complex as a high performance and recyclable catalyst for the synthesis of pyrano[3,2-RSC advances · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Both imidazolium and 1,2,4-triazolium cations are important functional moieties widely incorporated as building blocks in poly(ionic liquid)s (PILs). In a classical model, a PIL usually contains either imidazolium or 1,2,4-triazolium in its repeating unit. Herein, via exploiting the slight reactivity difference of alkyl bromide with imidazole and 1,2,4-triazole at room temperature, we synthesized dual-cationic PIL homopolymers carrying both imidazolium and 1,2,4-triazolium moieties in the same repeating unit, that is, an asymmetrically dicationic unit. We investigated their fundamental properties, for example, thermal stability and solubility, as well as their unique function in forming supramolecular porous membranes via a water-initiated phase-separation and cross-linking process. With such knowledge, we identified a water-based fabricate strategy toward air-stable porous membranes from single-component PILs. This study will enrich the design tools and chemical structure library of PILs and expand their application spectrum.
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Registered trials
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