ArticleJournal of the American Chemical Society2021
Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15.
Article in Journal of the American Chemical Society, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 96 papers.
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Who cites it
96 citing papers in PubMed.
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- Design Rules for Sb and Bi Porphyrin Capsules: Para-Substitution Effects and Pnictogen Bond Conformational Control.Inorganic chemistry · 2026Article
- Isolation of Potassium Bis(amido)diazadipnictogenide Salts.Organometallics · 2026Article
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- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
- Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides.Angewandte Chemie (International ed. in English) · 2026Article
- β-Vinylated Tri(1-adamantyl)phosphine: Synthesis, Characterization, and Application in Gold Catalysis.Chemistry, an Asian journal · 2026Article
- Multisite Proton-Coupled Electron Transfer Enables Iodanyl Radical Catalysis.Journal of the American Chemical Society · 2025Article
36 more citing papers are in PubMed but not listed here.
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Authors and funding
3 authors.
Funding
Abstract
A growing number of organopnictogen redox catalytic methods have emerged-especially within the past 10 years-that leverage the plentiful reversible two-electron redox chemistry within Group 15. The goal of this Perspective is to provide readers the context to understand the dramatic developments in organopnictogen catalysis over the past decade with an eye toward future development. An exposition of the fundamental differences in the atomic structure and bonding of the pnictogens, and thus the molecular electronic structure of organopnictogen compounds, is presented to establish the backdrop against which organopnictogen redox reactivity-and ultimately catalysis-is framed. A deep appreciation of these underlying periodic principles informs an understanding of the differing modes of organopnictogen redox catalysis and evokes the key challenges to the field moving forward. We close by addressing forward-looking directions likely to animate this area in the years to come. What new catalytic manifolds can be developed through creative catalyst and reaction design that take advantage of the intrinsic redox reactivity of the pnictogens to drive new discoveries in catalysis?
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