ArticleThe journal of physical chemistry. A2021
Controlling the Photostability of Pyrrole with Optical Nanocavities.
Article in The journal of physical chemistry. A, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Incorporating QM/MM Molecular Dynamics Into the Few-Mode Quantization Approach for Light-Matter Interactions in Nanophotonic Structures.Nanophotonics (Berlin, Germany) · 2026Article
- Impact of Dark Polariton States on Collective Strong Light-Matter Coupling in Molecules.The journal of physical chemistry letters · 2025Article
- Polariton mediated electron transfer under the collective molecule-cavity coupling regime.Chemical science · 2025Article
- Disentangling collective coupling in vibrational polaritons with double quantum coherence spectroscopy.The Journal of chemical physics · 2024Article
- Extending the Tavis-Cummings model for molecular ensembles-Exploring the effects of dipole self-energies and static dipole moments.The Journal of chemical physics · 2024Article
- Unraveling a Cavity-Induced Molecular Polarization Mechanism from Collective Vibrational Strong Coupling.The journal of physical chemistry letters · 2024Article
- Ab Initio Vibro-Polaritonic Spectra in Strongly Coupled Cavity-Molecule Systems.Journal of chemical theory and computation · 2023Article
- Cavity-Modified Chemiluminescent Reaction of Dioxetane.The journal of physical chemistry. A · 2023Article
- Understanding Polaritonic Chemistry from Ab Initio Quantum Electrodynamics.Chemical reviews · 2023Review
- Cavity Born-Oppenheimer Hartree-Fock Ansatz: Light-Matter Properties of Strongly Coupled Molecular Ensembles.The journal of physical chemistry letters · 2023Article
- Theoretical Advances in Polariton Chemistry and Molecular Cavity Quantum Electrodynamics.Chemical reviews · 2023Review
- Nonadiabatic Wave Packet Dynamics with Ab Initio Cavity-Born-Oppenheimer Potential Energy Surfaces.Journal of chemical theory and computation · 2023Article
- Time-resolved X-ray and XUV based spectroscopic methods for nonadiabatic processes in photochemistry.Chemical communications (Cambridge, England) · 2022Review
- Suppressing non-radiative decay of photochromic organic molecular systems in the strong coupling regime.Physical chemistry chemical physics : PCCP · 2022Article
- Triplet-triplet Annihilation Dynamics of Naphthalene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Theoretical Challenges in Polaritonic Chemistry.ACS photonics · 2022Review
- Capturing fingerprints of conical intersection: Complementary information of non-adiabatic dynamics from linear x-ray probes.Structural dynamics (Melville, N.Y.) · 2021Article
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Authors and funding
2 authors.
Funding
Abstract
Strong light-matter coupling provides a new strategy to manipulate the non-adiabatic dynamics of molecules by modifying potential energy surfaces. The vacuum field of nanocavities can couple strongly with the molecular degrees of freedom and form hybrid light-matter states, termed as polaritons or dressed states. The photochemistry of molecules possessing intrinsic conical intersections can be significantly altered by introducing cavity couplings to create new conical intersections or avoided crossings. Here, we explore the effects of optical cavities on the photo-induced hydrogen elimination reaction of pyrrole. Wave packet dynamics simulations have been performed on the two-state, two-mode model of pyrrole, combined with the cavity photon mode. Our results show how the optical cavities assist in controlling the photostability of pyrrole and influence the reaction mechanism by providing alternative dissociation pathways. The cavity effects have been found to be intensely dependent on the resonance frequency. We further demonstrate the importance of the vibrational cavity couplings and dipole-self interaction terms in describing the cavity-modified non-adiabatic dynamics.
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