ArticleAngewandte Chemie (International ed. in English)2021
Minimization of Back-Electron Transfer Enables the Elusive sp
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed.
- Remapping the Synthetic Landscape of α-Tertiary Alkylamines via Dual-Functional Catechol.Angewandte Chemie (International ed. in English) · 2026Article
- An alkyl-swap platform for late-stage modification of secondary N-methylamines.Nature chemistry · 2026Article
- Base-Mediated Degradation of Epoxy Thermosets via Carbon-Nitrogen Bond Cleavage for the Recovery of Amine Agents.ChemSusChem · 2026Article
- Radical defluoroallylation of polyfluoroalkyl compounds with alkenes via synergistic photoredox/cobalt catalysis.Nature communications · 2026Article
- Synthesis and crystal structure of HDAC6 selective inhibitor ofActa crystallographica. Section E, Crystallographic communications · 2026Article
- Merging Hydrogen-Atom-Transfer and the Truce-Smiles Rearrangement for Synthesis of β-Arylethylamines from Unactivated Allylsulfonamides.Angewandte Chemie (International ed. in English) · 2025Article
- Biomimetic Dehydrogenative Intermolecular Formal Allylic Amidation of Branched α-Olefins.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Solar overall water-splitting by a spin-hybrid all-organic semiconductor.Nature communications · 2024Article
- Straightforward synthesis of functionalized γ-Lactams using impure CONature communications · 2023Article
- Metal-free C-3 selective C(spRSC advances · 2023Article
- Mild and Functional Group-Tolerant AerobicThe Journal of organic chemistry · 2023Article
- Biomass-Derived Single Zn Atom Catalysts: The Multiple Roles of Single Zn Atoms in the Oxidative Cleavage of C-N Bonds.JACS Au · 2023Article
- Photoinduced Nickel-Catalyzed SelectiveJournal of the American Chemical Society · 2023Article
- Overcoming Back Electron Transfer in the Electron Donor-Acceptor Complex-Mediated Visible Light-Driven Generation of α-Aminoalkyl Radicals from Secondary Anilines.The Journal of organic chemistry · 2023Article
- Formation and degradation of strongly reducing cyanoarene-based radical anions towards efficient radical anion-mediated photoredox catalysis.Nature communications · 2023Article
- Merging Grubbs second-generation catalyst with photocatalysis enablesChemical science · 2022Article
- Alkyl Radical Generation via C-C Bond Cleavage in 2-Substituted Oxazolidines.ACS catalysis · 2022Article
- Synthesis of carbinoxamineChemical science · 2022Article
- Article
- Photoredox Cross-Dehydrogenative Coupling ofThe Journal of organic chemistry · 2022Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Anilines are some of the most used class of substrates for application in photoinduced electron transfer. N,N-Dialkyl-derivatives enable radical generation α to the N-atom by oxidation followed by deprotonation. This approach is however elusive to monosubstituted anilines owing to fast back-electron transfer (BET). Here we demonstrate that BET can be minimised by using photoredox catalysis in the presence of an exogenous alkylamine. This approach synergistically aids aniline SET oxidation and then accelerates the following deprotonation. In this way, the generation of α-anilinoalkyl radicals is now possible and these species can be used in a general sense to achieve divergent sp
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.