ArticlePolymer chemistry2020
Impacts of Performing Electrolysis During Organocatalyzed Atom Transfer Radical Polymerization.
Article in Polymer chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
2 citing papers in PubMed.
- Radical Cations of Phenoxazine and Dihydrophenazine Photoredox Catalysts and Their Role as Deactivators in Organocatalyzed Atom Transfer Radical Polymerization.Macromolecules · 2021Article
- Solvent Effects and Side Reactions in Organocatalyzed Atom Transfer Radical Polymerization for Enabling the Controlled Polymerization of Acrylates Catalyzed by Diaryl Dihydrophenazines.Macromolecules · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
An electrochemical variant of organocatalyzed atom transfer radical polymerization (O-ATRP) is developed and investigated. Inspired by electrochemically mediated atom transfer radical polymerization (eATRP), potentiostatic electrolysis is used to manipulate the catalyst's redox states in O-ATRP to understand whether deactivation in O-ATRP can be enhanced to improve polymerization control. During the course of this work, several possible side reactions are investigated, and the electrochemical apparatus is optimized to reduce side reactions at the counter electrode. This electrochemically modified O-ATRP method (eO-ATRP) is then studied at different applied potentials, under different irradiation conditions, and with two photoredox catalysts to understand the impact of electrolysis on polymerization control. Ultimately, although electrolysis was successfully used to improve polymerization control in O-ATRP, some additional challenges have been identified. Several key questions are postulated to guide future work in this area.
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Registered trials
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