Evidence map›Paper›PMID 33448577›Full record

ArticleAngewandte Chemie (International ed. in English)2020

Reversible Hydride Migration from C

Macarena G Alférez, Juan J Moreno, Nereida Hidalgo, Jesús Campos

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed.

  1. Opposite Effects of Added AsPhInorganic chemistry · 2025
    Article
  2. Article
  3. Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.Dalton transactions (Cambridge, England : 2003) · 2024
    Review
  4. Article
  5. Article
  6. Article
  7. Review
  8. Divergent COAngewandte Chemie (International ed. in English) · 2022
    Article
  9. Article
  10. Article
  11. Review
  12. Article
  13. Reversible Hydride Migration from CAngewandte Chemie (International ed. in English) · 2020
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Macarena G AlférezInstituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC), University of Sevilla, Avenida Américo Vespucio 49, 41092, Sevilla, Spain.
Juan J MorenoInstituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC), University of Sevilla, Avenida Américo Vespucio 49, 41092, Sevilla, Spain.
Nereida HidalgoInstituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC), University of Sevilla, Avenida Américo Vespucio 49, 41092, Sevilla, Spain.
Jesús CamposInstituto de Investigaciones Químicas (IIQ), Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Consejo Superior de Investigaciones Científicas (CSIC), University of Sevilla, Avenida Américo Vespucio 49, 41092, Sevilla, Spain.ORCID http://orcid.org/0000-0002-5155-1262

Funding

European Research Council ERC Starting Grant, CoopCat, Project 756575
6 · The paper itself

Abstract

The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non-innocent behaviour are being documented. Here, we provide evidence for reversible intramolecular C-H activation at one methyl terminus of C

Indexed as

cyclopentadienyl ligandshydride migrationmetal–ligand cooperationnon-innocent ligandstransition metals

Identifiers

PMID33448577
PMCPMC7754342

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.