ArticleNanomaterials (Basel, Switzerland)2021
Nanothermodynamic Description and Molecular Simulation of a Single-Phase Fluid in a Slit Pore.
Article in Nanomaterials (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 18 citations in OpenAlex.
- A Nanothermodynamic Approach to the Shuttleworth and Lippman Equations.Entropy (Basel, Switzerland) · 2026Article
- Nanothermodynamics: There's Plenty of Room on the Inside.Nanomaterials (Basel, Switzerland) · 2024Review
- Pressure Anisotropy in Polymer Brushes and Its Effects on Wetting.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Nanoscale thermodynamics needs the concept of a disjoining chemical potential.Nature communications · 2023Article
- Thermodynamics, statistical mechanics and the vanishing pore width limit of confined fluids.Communications physics · 2023Article
- Legendre-Fenchel transforms capture layering transitions in porous media.Nanoscale advances · 2022Article
- Special Issue on Nanoscale Thermodynamics.Nanomaterials (Basel, Switzerland) · 2021Article
Corrections and comments
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Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
We have described for the first time the thermodynamic state of a highly confined single-phase and single-component fluid in a slit pore using Hill's thermodynamics of small systems. Hill's theory has been named nanothermodynamics. We started by constructing an ensemble of slit pores for controlled temperature, volume, surface area, and chemical potential. We have presented the integral and differential properties according to Hill, and used them to define the disjoining pressure on the new basis. We identified all thermodynamic pressures by their mechanical counterparts in a consistent manner, and have given evidence that the identification holds true using molecular simulations. We computed the entropy and energy densities, and found in agreement with the literature, that the structures at the wall are of an energetic, not entropic nature. We have shown that the subdivision potential is unequal to zero for small wall surface areas. We have showed how Hill's method can be used to find new Maxwell relations of a confined fluid, in addition to a scaling relation, which applies when the walls are far enough apart. By this expansion of nanothermodynamics, we have set the stage for further developments of the thermodynamics of confined fluids, a field that is central in nanotechnology.
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