ArticleNature communications2021
Integrating single-cobalt-site and electric field of boron nitride in dechlorination electrocatalysts by bioinspired design.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers, 1 of them a synthesis that pooled it.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
22 citing papers in PubMed, 1 synthesis or guideline pooled it.
- Precision Design of Single-Atom Catalysts for High-Performance Biosensors.Chemical record (New York, N.Y.) · 2026Pooled it
- In-situ chlorine radical generation from captured ClNature communications · 2026Article
- Electronic-State Engineering of Transition Metals Regulates Decomposition Kinetics of LiChemSusChem · 2026Article
- Dynamic chloride coordination enables selective pulsed electrocatalytic upcycling of 4-chlorophenol on FeNNature communications · 2026Article
- Steering Electron Transport in Intrinsically Piezoelectric Covalent Organic Frameworks for Efficient COAngewandte Chemie (International ed. in English) · 2026Article
- Cobalt-modified graphitic carbon nitride nanosheets for the photocatalytic degradation of diclofenac.Frontiers in chemistry · 2026Article
- Bioinspired Design of Heterogenous Single-Atomic-Site Catalysts for Electrocatalysis and Photocatalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Enhanced proton-feeding kinetics of metal-organic framework toward industrial-level HNature communications · 2025Article
- Vacancy Engineered Zero-Valent Iron Steer Hydrogen Spillover toward Per- and Polychlorinated Organics Rapid Complete Dechlorination.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Pd single atoms guided proton transfer along an interfacial hydrogen bond network for efficient electrochemical hydrogenation.Science advances · 2025Article
- Modulating the local microenvironment over isolated nickel sites through first-shell coordination to regulate the reaction pathway of CONational science review · 2025Article
- Burning question: Rethinking organohalide degradation strategy for bioremediation applications.Microbial biotechnology · 2024Review
- Few-femtosecond electronic and structural rearrangements ofStructural dynamics (Melville, N.Y.) · 2023Article
- Mimicking reductive dehalogenases for efficient electrocatalytic water dechlorination.Nature communications · 2023Article
- Manipulating local coordination of copper single atom catalyst enables efficient CONature communications · 2023Article
- Strong ferromagnetism of g-CNature communications · 2023Article
- Ampere-level current density ammonia electrochemical synthesis using CuCo nanosheets simulating nitrite reductase bifunctional nature.Nature communications · 2022Article
- Microenvironment engineering of supported metal nanoparticles for chemoselective hydrogenation.Chemical science · 2022Review
- Article
- Recent Progress in Fabrication and Application of BN Nanostructures and BN-Based Nanohybrids.Nanomaterials (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The construction of enzyme-inspired artificial catalysts with enzyme-like active sites and microenvironment remains a great challenge. Herein, we report a single-atomic-site Co catalyst supported by carbon doped boron nitride (BCN) with locally polarized B-N bonds (Co SAs/BCN) to simulate the reductive dehalogenases. Density functional theory analysis suggests that the BCN supports, featured with ionic characteristics, provide additional electric field effect compared with graphitic carbon or N-doped carbon (CN), which could facilitate the adsorption of polarized organochlorides. Consistent with the theoretical results, the Co SAs/BCN catalyst delivers a high activity with nearly complete dechlorination (~98%) at a potential of -0.9 V versus Ag/AgCl for chloramphenicol (CAP), showing that the rate constant (k) contributed by unit mass of metal (k/ratio) is 4 and 19 times more active than those of the Co SAs/CN and state-of-the-art Pd/C catalyst, respectively. We show that Co single atoms coupled with BCN host exhibit high stability and selectivity in CAP dechlorination and suppress the competing hydrogen evolution reaction, endowing the Co SAs/BCN as a candidate for sustainable conversion of organic chloride.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.