ArticleNature communications2021
Excited-state vibration-polariton transitions and dynamics in nitroprusside.
Article in Nature communications, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Reservoir Dynamics in Vibrational Polaritons Revealed by Detuning-Dependent Ultrafast Spectroscopy.The journal of physical chemistry letters · 2026Article
- Phase-Resolved Two-Dimensional Infrared Spectroscopy of Solution-Phase Vibrational Polaritons on Gold Antenna Meta-Surfaces.The journal of physical chemistry letters · 2026Article
- Efficient and tunable photochemical charge transfer via long-lived Bloch surface wave polaritons.Nature nanotechnology · 2025Article
- Excited State Dynamics of COJournal of the American Chemical Society · 2025Article
- Theoretical and quantum mechanical deconstruction of vibrational energy transfer pathways modified by collective vibrational strong coupling.Nature communications · 2025Article
- Probing the anharmonicity of vibrational polaritons with double-quantum two-dimensional infrared spectroscopy.Nanophotonics (Berlin, Germany) · 2024Article
- The role of IR inactive mode in W(CO)Nanophotonics (Berlin, Germany) · 2024Article
- Ultrafast Spectroscopy under Vibrational Strong Coupling in Diphenylphosphoryl Azide.The journal of physical chemistry. A · 2024Article
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
- Manipulating hydrogen bond dissociation rates and mechanisms in water dimer through vibrational strong coupling.Nature communications · 2023Article
- Antenna-coupled infrared nanospectroscopy of intramolecular vibrational interaction.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Molecular Vibrational Polariton Dynamics: What Can Polaritons Do?Accounts of chemical research · 2023Article
- Comment on "Isolating Polaritonic 2D-IR Transmission Spectra".The journal of physical chemistry letters · 2023Article
- Enabling multiple intercavity polariton coherences by adding quantum confinement to cavity molecular polaritons.Proceedings of the National Academy of Sciences of the United States of America · 2023Article
- Energy cascades in donor-acceptor exciton-polaritons observed by ultrafast two-dimensional white-light spectroscopy.Nature communications · 2022Article
- Optical cavity-mediated exciton dynamics in photosynthetic light harvesting 2 complexes.Nature communications · 2022Article
- Energy-efficient pathway for selectively exciting solute molecules to high vibrational states via solvent vibration-polariton pumping.Nature communications · 2022Article
- Ab Initio Linear-Response Approach to Vibro-Polaritons in the Cavity Born-Oppenheimer Approximation.Journal of chemical theory and computation · 2022Article
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Strong cavity coupling to molecular vibrations creates vibration-polaritons capable of modifying chemical reaction kinetics, product branching ratios, and charge transfer equilibria. However, the mechanisms impacting these molecular processes remain elusive. Furthermore, even basic elements determining the spectral properties of polaritons, such as selection rules, transition moments, and lifetimes are poorly understood. Here, we use two-dimensional infrared and filtered pump-probe spectroscopy to report clear spectroscopic signatures and relaxation dynamics of excited vibration-polaritons formed from the cavity-coupled NO band of nitroprusside. We apply an extended multi-level quantum Rabi model that predicts transition frequencies and strengths that agree well with our experiment. Notably, the polariton features decay ~3-4 times slower than the polariton dephasing time, indicating that they support incoherent population, a consequence of their partial matter character.
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