Evidence map›Paper›PMID 33406753›Full record

ArticleMolecules (Basel, Switzerland)2021

Enantioseparation of 5,5'-Dibromo-2,2'-Dichloro-3-Selanyl-4,4'-Bipyridines on Polysaccharide-Based Chiral Stationary Phases: Exploring Chalcogen Bonds in Liquid-Phase Chromatography.

Paola Peluso, Alessandro Dessì, Roberto Dallocchio, Barbara Sechi, Carlo Gatti, Bezhan Chankvetadze, Victor Mamane, Robin Weiss, Patrick Pale, Emmanuel Aubert and 1 more

Abstract read
In one paragraph

Article in Molecules (Basel, Switzerland), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Review
  4. Rapid Access to Chiral and Tripodal Cavitands from β-Pinene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Article
  5. Stereoselective Processes Based on σ-Hole Interactions.Molecules (Basel, Switzerland) · 2022
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Paola PelusoInstitute of Biomolecular Chemistry ICB, CNR, Secondary Branch of Sassari, Traversa La Crucca 3, Regione Baldinca, Li Punti, 07100 Sassari, Italy.ORCID 0000-0003-3489-3428
Alessandro DessìInstitute of Biomolecular Chemistry ICB, CNR, Secondary Branch of Sassari, Traversa La Crucca 3, Regione Baldinca, Li Punti, 07100 Sassari, Italy.ORCID 0000-0001-8258-7332
Roberto DallocchioInstitute of Biomolecular Chemistry ICB, CNR, Secondary Branch of Sassari, Traversa La Crucca 3, Regione Baldinca, Li Punti, 07100 Sassari, Italy.ORCID 0000-0003-4626-4792
Barbara SechiInstitute of Biomolecular Chemistry ICB, CNR, Secondary Branch of Sassari, Traversa La Crucca 3, Regione Baldinca, Li Punti, 07100 Sassari, Italy.
Carlo GattiCNR-SCITEC, Istituto di Scienze e Tecnologie Chimiche "Giulio Natta", sezione di via Golgi, via C. Golgi 19, 20133 Milano, Italy.ORCID 0000-0002-0047-1596
Bezhan ChankvetadzeInstitute of Physical and Analytical Chemistry, School of Exact and Natural Sciences, Tbilisi State University, Chavchavadze Ave 3, 0179 Tbilisi, Georgia.
Victor MamaneStrasbourg Institute of Chemistry, UMR CNRS 7177, Team LASYROC, 1 rue Blaise Pascal, University of Strasbourg, 67008 Strasbourg CEDEX, France.ORCID 0000-0001-8996-7880
Robin WeissStrasbourg Institute of Chemistry, UMR CNRS 7177, Team LASYROC, 1 rue Blaise Pascal, University of Strasbourg, 67008 Strasbourg CEDEX, France.
Patrick PaleStrasbourg Institute of Chemistry, UMR CNRS 7177, Team LASYROC, 1 rue Blaise Pascal, University of Strasbourg, 67008 Strasbourg CEDEX, France.ORCID 0000-0002-3924-530X
Emmanuel AubertCrystallography, Magnetic Resonance and Modelling (CRM2), UMR CNRS 7036, University of Lorraine, Bd des Aiguillettes, 54506 Vandoeuvre-les-Nancy, France.ORCID 0000-0001-7860-1349
Sergio CossuDepartment of Molecular Sciences and Nanosystems DSMN, Venice Ca' Foscari University, Via Torino 155, 30172 Mestre Venezia, Italy.ORCID 0000-0003-0088-5227

Funding

International Center Frontier Research in Chemistry (icFRC), the LabEx CSC ANR-10-LABX-0026 CSCUniversity Ca' Foscari Venice ADIR
6 · The paper itself

Abstract

The chalcogen bond (ChB) is a noncovalent interaction based on electrophilic features of regions of electron charge density depletion (σ-holes) located on bound atoms of group VI. The σ-holes of sulfur and heavy chalcogen atoms (Se, Te) (donors) can interact through their positive electrostatic potential (

Indexed as

ThermodynamicsChalcogensChromatography, LiquidHeterocyclic CompoundsPolysaccharidesPyridinesStatic ElectricityStereoisomerismChalcogensHeterocyclic CompoundsPolysaccharidesPyridinesbipyridineschalcogen bondelectrostatic potentialenantioseparationhigh-performance liquid chromatographypolysaccharide-based chiral stationary phases

Identifiers

PMID33406753
PMCPMC7794968

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.