ReviewChemical science2020
Catalytic generation of alkoxy radicals from unfunctionalized alcohols.
Review in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 44 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
44 citing papers in PubMed.
- Adaptive Zinc-Amide Catalysis Enables C(spJACS Au · 2026Article
- Direct δ-Lactone Synthesis From Free Alcohols via Photoinduced δ-C(spAngewandte Chemie (International ed. in English) · 2026Article
- Photocatalytic Site- and Stereoselective Functionalization of Carbohydrates.Chemical record (New York, N.Y.) · 2026Review
- β-Scission of Tertiary Alcohols on a Platinum-Loaded Titanium Dioxide Photocatalyst for C─C Bond-Forming Reactions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Activation of alcohols as sulfonium salts in the photocatalytic hetero-difunctionalization of alkenes.Nature chemistry · 2026Article
- Organophotoredox Dioxygenation of Alkenes via ROH···F-ActivatedOrganic letters · 2025Article
- Photocatalytic Aqueous Reforming of Methyl Formate.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Deconstructive Radical-Radical Coupling for Programmable Remote Acylation.Angewandte Chemie (International ed. in English) · 2025Article
- Electro-oxidative amination of benzylic C(sp³)-C(sp³) bonds in aromatic hydrocarbons.Nature communications · 2025Article
- Light-Driven C(spAccounts of chemical research · 2025Article
- Organic photoredox-catalyzed unimolecular PCET of benzylic alcohols.Chemical science · 2025Article
- Diversified Fluoroalkylation of Alkenes Using Quaternary Fluoroalkyl Alcohols as the Fluoroalkylating Reagents.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Iron-Catalyzed Aerobic Carbonylation of Methane via Ligand-to-Metal Charge Transfer Excitation.Journal of the American Chemical Society · 2025Article
- Hydroalkylation of unactivated olefins with C(spScience advances · 2024Article
- General Alkene 1,2-Journal of the American Chemical Society · 2024Article
- Decarboxylative Cross-Coupling Enabled by Fe and Ni Metallaphotoredox Catalysis.Journal of the American Chemical Society · 2024Article
- Ligand-to-Metal Charge Transfer (LMCT) Catalysis: Harnessing Simple Cerium Catalysts for Selective Functionalization of Inert C-H and C-C Bonds.Accounts of chemical research · 2024Article
- Revealing the nature of covalently tethered distonic radical anions in the generation of heteroatom-centered radicals: evidence for the polarity-matching PCET pathway.Chemical science · 2024Article
- Accessing Alkoxy Radicals via Frustrated Radical Pairs: Diverse Oxidative Functionalizations of Tertiary Alcohols.Journal of the American Chemical Society · 2024Article
- Visible-Light-Mediated Ring-Opening Geminal Dibromination of Alkenes via Alkoxy Radicals Enabled by Electron Donor-Acceptor Complex.Molecules (Basel, Switzerland) · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Alkoxy radicals have long been recognized as powerful synthetic intermediates with well-established reactivity patterns. Due to the high bond dissociation free energy of aliphatic alcohol O-H bonds, these radicals are difficult to access through direct homolysis, and conventional methods have instead relied on activation of O-functionalized precursors. Over the past decade, however, numerous catalytic methods for the direct generation of alkoxy radicals from simple alcohol starting materials have emerged and created opportunities for the development of new transformations. This minireview discusses recent advances in catalytic alkoxy radical generation, with particular emphasis on progress toward the direct activation of unfunctionalized alcohols enabled by transition metal and photoredox catalysis.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.