ArticleProceedings of the National Academy of Sciences of the United States of America2021
Strong metal-metal Pauli repulsion leads to repulsive metallophilicity in closed-shell d
Article in Proceedings of the National Academy of Sciences of the United States of America, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- The Metallophilicity Phenomenon: The Interplay of Steric, Orbital, Dispersion, and Electronic Correlation Effects in Closed-Shell Metal-Metal Contacts.Inorganic chemistry · 2026Article
- Computational Characterization of Unsupported Au(I)···Ir(I) Metallophilic Interactions: Evidence for Strong Dispersive Stabilization.Inorganic chemistry · 2025Article
- Unraveling Unsupported Gold···Platinum Metallophilic Interactions: An In-Depth Computational and Topological Study.Inorganic chemistry · 2025Article
- Parity-forbidden superatomic molecular orbital interaction and aurophilicity induced H─Au bonding in H@AuScience advances · 2025Article
- Heterobimetallic Complexes That Point to When Bond Dissociation Energies Deviate from Computational Expectations.Journal of the American Chemical Society · 2025Article
- Aurophilic interaction-based aggregation of gem-digold(I) aryls towards high spin-orbit coupling and strong phosphorescence.Nature communications · 2025Article
- Molecular Interactions in Atomically Precise Metal Nanoclusters.Precision chemistry · 2024Review
- The nature of metallophilic interactions in closed-shell dPhysical chemistry chemical physics : PCCP · 2024Article
- Dispersion Control over Molecule Cohesion: Exploiting and Dissecting the Tipping Power of Aromatic Rings.Accounts of chemical research · 2024Article
- Where are the Excess Electrons in Subvalent Compounds? The Case of AgInorganic chemistry · 2024Article
- Noble Metal Nanoparticles with Nanogel Coatings: Coinage Metal Thiolate-Stabilized Glutathione Hydrogel Shells.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Closed-shell dRSC advances · 2024Article
- Structure and bonding in rhodium coordination compounds: aChemical science · 2024Article
- Metallophilic Interactions Drive Supramolecular Chirality Evolution and Amplify Circularly Polarized Luminescence.JACS Au · 2023Article
- Article
- Structure-property relationships of photofunctional diiridium(II) complexes with tetracationic charge and an unsupported Ir-Ir bond.Communications chemistry · 2022Article
- Revisiting the Bonding Model for Gold(I) Species: The Importance of Pauli Repulsion Revealed in a Gold(I)-Cyclobutadiene Complex.Angewandte Chemie (International ed. in English) · 2022Article
- Layered post-transition-metal dichalcogenide SnGeRSC advances · 2022Article
- Elucidation of the key role of Pt···Pt interactions in the directional self-assembly of platinum(II) complexes.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Closed-shell dRSC advances · 2022Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metallophilicity is defined as the interaction among closed-shell metal centers, the origin of which remains controversial, particularly for the roles of spd orbital hybridization (mixing of the spd atomic orbitals of the metal atom in the molecular orbitals of metal complex) and the relativistic effect. Our studies reveal that at close M-M' distances in the X-ray crystal structures of d
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