ArticleACS photonics2020
Impact of Vibrational Modes in the Plasmonic Purcell Effect of Organic Molecules.
Article in ACS photonics, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed.
- Semianalytical Treatment of Collective Vibrational Strong Coupling in Infrared Phononic and Plasmonic Nanoantennas.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Nanocavities for Molecular Optomechanics: Their Fundamental Description and Applications.ACS photonics · 2024Review
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
- Pyramidal hyperbolic metasurfaces enhance spontaneous emission of nitrogen-vacancy centers in nanodiamond.Advanced optical materials · 2023Article
- A Theoretical Perspective on Molecular Polaritonics.ACS photonics · 2022Review
- Theoretical Challenges in Polaritonic Chemistry.ACS photonics · 2022Review
- Plexcitonic Quantum Light Emission from Nanoparticle-on-Mirror Cavities.Nano letters · 2022Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
By means of quantum tensor network calculations, we investigate the large Purcell effect experienced by an organic molecule placed in the vicinity of a plasmonic nanostructure. In particular, we consider a donor-π bridge-acceptor dye at the gap of two Ag nanospheres. Our theoretical approach allows for a realistic description of the continua of both molecular vibrations and optical nanocavity modes. We analyze both the ultrafast exciton dynamics in the large Purcell enhancement regime and the corresponding emission spectrum, showing that these magnitudes are not accurately represented by the simplified models used up to date. Specifically, both the two-level system model and the single vibrational mode model can only reproduce the dynamics over short time scales, whereas the Fermi's golden rule approach accounts only for the behavior at very long times. We demonstrate that including the whole set of vibrational modes is necessary to capture most of the dynamics and the corresponding spectrum. Moreover, by disentangling the coupling of the molecule to radiative and nonradiative plasmonic modes, we also shed light into the quenching phenomenology taking place in the system.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.