Evidence map›Paper›PMID 33354969›Full record

ArticleOrganic letters2021

Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride.

Sungjin Kim, Yaroslav Khomutnyk, Anton Bannykh, Pavel Nagorny

Open access · greenAbstract read
In one paragraph

Article in Organic letters, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.

0numbers the graph read from it
0cells of the map it votes in
15citing papers in PubMed
2.5field-weighted citation impact, top 11% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

15 citing papers in PubMed, 64 citations in OpenAlex.

  1. Photocatalytic Synthesis of Pentafluorosulfanyl Ketones, Acetals, and BCP Motifs Utilizing SFAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026
    Article
  2. Article
  3. Bimetallic Activation of SFInorganic chemistry · 2025
    Article
  4. Article
  5. Activation and Catalytic Degradation of SFJournal of the American Chemical Society · 2024
    Article
  6. Review
  7. Review
  8. Article
  9. Activation of SFMolecules (Basel, Switzerland) · 2023
    Article
  10. Article
  11. Review
  12. Review
  13. Article
  14. Review
  15. Complete deconstruction of SFChemical communications (Cambridge, England) · 2021
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 1 country.

Sungjin KimDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109, United States.
Yaroslav KhomutnykDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109, United States.
Anton BannykhDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109, United States.
Pavel NagornyDepartment of Chemistry, University of Michigan, 930 N. University Ave., Ann Arbor, Michigan 48109, United States.ORCID 0000-0002-7043-984X
University of Michigan · US

Funding

Catalytic Methods for Building Block Assembly and for Stereoselective GlycosylationU01GM125274 · NIGMS · UNIVERSITY OF MICHIGAN AT ANN ARBOR · PI MONTGOMERY, JOHN, NAGORNY, PAVEL · 2017 to 2020
$2.3M
NIGMS NIH HHS U01 GM125274
6 · The paper itself

Abstract

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4'-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.

Indexed as

FluoridesHalogenationMolecular StructureSulfurFluoridesSulfur

Identifiers

PMID33354969
PMCPMC7783729
OpenAlexW3116393517

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.