Evidence map›Paper›PMID 33348460›Full record

ArticleAngewandte Chemie (International ed. in English)2021

A Pseudotetrahedral Terminal Oxoiron(IV) Complex: Mechanistic Promiscuity in C-H Bond Oxidation Reactions.

Katrin Warm, Alice Paskin, Uwe Kuhlmann, Eckhard Bill, Marcel Swart, Michael Haumann, Holger Dau, Peter Hildebrandt, Kallol Ray

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.

0numbers the graph read from it
0cells of the map it votes in
20citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

20 citing papers in PubMed.

  1. Review
  2. Review
  3. Article
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  5. Article
  6. Article
  7. Disentangling Driving Force Effects, Polar Effects,Journal of the American Chemical Society · 2025
    Article
  8. A 5,000-fold increase in the HAT reactivity of a nonheme FeProceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  9. 10-Fold Increase in Hydrogen Atom Transfer Reactivity for a Series ofJournal of the American Chemical Society · 2025
    Article
  10. Article
  11. Article
  12. NMR and Mössbauer Studies Reveal a Temperature-Dependent Switch fromJournal of the American Chemical Society · 2024
    Article
  13. Article
  14. Nonheme FeInorganic chemistry · 2023
    Article
  15. Highly selective synthesis of surface FeProceedings of the National Academy of Sciences of the United States of America · 2023
    Article
  16. Article
  17. Determination of the iron(IV) local spin states of the Q intermediate of soluble methane monooxygenase by Kβ X-ray emission spectroscopy.Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry · 2022
    Article
  18. Article
  19. A Reactive, Photogenerated High-Spin (Journal of the American Chemical Society · 2021
    Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Katrin WarmInstitut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489, Berlin, Germany.ORCID 0000-0002-1894-2165
Alice PaskinInstitut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489, Berlin, Germany.ORCID 0000-0003-3892-0278
Uwe KuhlmannInstitut für Chemie, Technische Universität Berlin, Fakultät II, Straße des 17. Juni 135, 10623, Berlin, Germany.
Eckhard BillMax-Planck-Institut für Chemische Energiekonversion (CEC), Stiftstraße 34-36, 45470, Mülheim, Germany.ORCID 0000-0001-9138-3964
Marcel SwartInstitut de Química Computacional i Catàlisi, Universitat de Girona, Campus Montilivi (Ciències), Maria Aurèlia Capmany i Farnés, 69, 17003, Girona, Spain.ORCID 0000-0002-8174-8488
Michael HaumannInstitut für Physik, Freie Universität Berlin, Arnimallee 14, 14195, Berlin, Germany.ORCID 0000-0001-7008-1764
Holger DauInstitut für Physik, Freie Universität Berlin, Arnimallee 14, 14195, Berlin, Germany.ORCID 0000-0001-6482-7494
Peter HildebrandtInstitut für Chemie, Technische Universität Berlin, Fakultät II, Straße des 17. Juni 135, 10623, Berlin, Germany.ORCID 0000-0003-1030-5900
Kallol RayInstitut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489, Berlin, Germany.ORCID 0000-0003-2074-8844

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

S=2 oxoiron(IV) species act as reactive intermediates in the catalytic cycle of nonheme iron oxygenases. The few available synthetic S=2 Fe

Indexed as

bioinorganic chemistryelectron transferenzyme modelshigh-valent ironhydrogen atom abstraction

Identifiers

PMID33348460
PMCPMC7985879

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.