ArticleNature chemistry2021
Isolation and electronic structures of derivatized manganocene, ferrocene and cobaltocene anions.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed, 69 citations in OpenAlex.
- The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane.Angewandte Chemie (International ed. in English) · 2026Article
- Inorganic Cobalt Sandwich Complex [(ηJournal of the American Chemical Society · 2026Article
- A Guide to Nonaqueous Electrochemistry of f-Element Complexes.Inorganic chemistry · 2026Article
- Inverse palladocenes.Nature communications · 2026Article
- Review
- Coexistence of Metallocene Cations and Anions.Journal of the American Chemical Society · 2025Article
- Ferrocene-Functionalized Black Phosphorus Nanoplatform Enables Targeted and Prolonged MRI Visualization of Atherosclerotic Plaques.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Unlocking a Ferrocenium Superoxidizer with the Perfluorinated Cp* Ligand.Angewandte Chemie (International ed. in English) · 2025Article
- From 18- to 20-electron ferrocene derivatives via ligand coordination.Nature communications · 2025Article
- Multi-Ferrocene-Based Ligands: From Design to Applications.Chemical reviews · 2025Review
- Coordination-Induced Magnetism Strategy for Highly Selective and Efficient Uranium Separation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Ultrafast photogeneration of a metal-organic nitrene from 1,1'-diazidoferrocene.Chemical science · 2024Article
- Electronic Structure of Three-Coordinate FeInorganic chemistry · 2024Article
- Low-Valent Transition Metalate Anions in Synthesis, Small Molecule Activation, and Catalysis.Chemical reviews · 2024Review
- Synthesis and characterization of a formal 21-electron cobaltocene derivative.Nature communications · 2023Article
- Bis(imidazolium)-1,3-diphosphete-diide: A Building Block for FeCAngewandte Chemie (International ed. in English) · 2022Article
- Bulking up CpOrganometallics · 2022Article
- Progress and Prospect of Organic Electrocatalysts in Lithium-Sulfur Batteries.Frontiers in chemistry · 2021Review
Corrections and comments
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Authors and funding
9 authors at 3 institutions in 2 countries.
Funding
Abstract
The discovery of ferrocene nearly 70 years ago marked the genesis of metallocene chemistry. Although the ferrocenium cation was discovered soon afterwards, a derivatized ferrocenium dication was only isolated in 2016 and the monoanion of ferrocene has only been observed in low-temperature electrochemical studies. Here we report the isolation of a derivatized ferrocene anion in the solid state as part of an isostructural family of 3d metallocenates, which consist of anionic complexes of a metal centre (manganese, iron or cobalt) sandwiched between two bulky Cp
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