ArticleProceedings of the National Academy of Sciences of the United States of America2020
An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Attractive Noncovalent Interactions versus Steric Confinement in Asymmetric Supramolecular Catalysis.Journal of the American Chemical Society · 2026Article
- Terahertz calorimetry spotlights the role of water in biological processes.Nature reviews. Chemistry · 2025Review
- Dichotomous behavior of water in binary mixtures with a turning point between 40 and 60 °C.RSC advances · 2025Article
- TinkerModeller: An Efficient Tool for Building Biological Systems in Tinker Simulations.Journal of chemical theory and computation · 2025Article
- Self-Assembled Iron(III) Coordination Cage as an MRI-Active Carrier for a Gold(I) Drug.Bioconjugate chemistry · 2024Article
- Tuning Acid-Base Chemistry at an Electrified Gold/Water Interface.Journal of the American Chemical Society · 2024Article
- Hydration water drives the self-assembly of guanosine monophosphate.Biophysical journal · 2024Article
- Tunable Electrochemical Entropy through Solvent Ordering by a Supramolecular Host.Journal of the American Chemical Society · 2023Article
- A porphyrin-based molecular cage guided by designed local-electric field is highly selective and efficient.Chemical science · 2023Article
- Quantifying the Effect of Guest Binding on Host Environment.Journal of the American Chemical Society · 2023Article
- Water structure modification by d-(+)-glucose at different concentrations and temperatures-effect of mutarotation.RSC advances · 2023Article
- Catalysis by [GaChemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Selective separation of planar and non-planar hydrocarbons using an aqueous PdChemical science · 2022Article
- Spectroscopic Fingerprints of Cavity Formation and Solute Insertion as a Measure of Hydration Entropic Loss and Enthalpic Gain.Angewandte Chemie (International ed. in English) · 2022Article
- Modeling Kinetics and Thermodynamics of Guest Encapsulation into the [MJournal of chemical information and modeling · 2021Article
- Molecular Fingerprints of Hydrophobicity at Aqueous Interfaces from Theory and Vibrational Spectroscopies.The journal of physical chemistry letters · 2021Article
- Kinetic effects of molecular clustering and solvation by extended networks in zeolite acid catalysis.Chemical science · 2021Review
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Authors and funding
10 authors.
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Abstract
Water under nanoconfinement at ambient conditions has exhibited low-dimensional ice formation and liquid-solid phase transitions, but with structural and dynamical signatures that map onto known regions of water's phase diagram. Using terahertz (THz) absorption spectroscopy and ab initio molecular dynamics, we have investigated the ambient water confined in a supramolecular tetrahedral assembly, and determined that a dynamically distinct network of 9 ± 1 water molecules is present within the nanocavity of the host. The low-frequency absorption spectrum and theoretical analysis of the water in the Ga
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