ArticleDalton transactions (Cambridge, England : 2003)2021
C-Term magnetic circular dichroism (MCD) spectroscopy in paramagnetic transition metal and f-element organometallic chemistry.
Article in Dalton transactions (Cambridge, England : 2003), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Magneto-Optical Spectroscopy Across Three Oxidation States of a Europium Terpyridine Complex.Inorganic chemistry · 2026Article
- Exploring a New Family of (Phosphinochalcogenoyl)Europocenes for Magneto-Optical Thermometry.Angewandte Chemie (International ed. in English) · 2025Article
- Photoluminescence of a Uranium(IV) Alkoxide Complex.JACS Au · 2025Article
- Understanding covalency in molecular f-block compounds from the synergy of spectroscopy and quantum chemistry.Nature reviews. Chemistry · 2024Review
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Abstract
Magnetic circular dichroism (MCD) spectroscopy is a powerful experiment used to probe the electronic structure and bonding in paramagnetic metal-based complexes. While C-term MCD spectroscopy has been utilized in many areas of chemistry, it has been underutilized in studying paramagnetic organometallic transition metal and f-element complexes. From the analysis of isolated organometallic complexes to the study of in situ generated species, MCD can provide information regarding ligand interactions, oxidation and spin state, and geometry and coordination environment of paramagnetic species. The pratical aspects of this technique, such as air-free sample preparation and cryogenic experimental temperatures, allow for the study of highly unstable species, something that is often difficult with other spectroscopic techniques. This perspective highlights MCD studies of both transition metal and f-element organometallic complexes, including in situ generated reactive intermediates, to demonstrate the utility of this technique in probing electronic structure, bonding and mechanism in paramagnetic organometallic chemistry.
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