Evidence map›Paper›PMID 33306228›Full record

ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021

Photocatalyzed Transition-Metal-Free Oxidative Cross-Coupling Reactions of Tetraorganoborates*.

Arif Music, Andreas N Baumann, Florian Boser, Nicolas Müller, Florian Matz, Thomas C Jagau, Dorian Didier

Abstract read
In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Article
  2. Zweifel olefination for C-glycosylation.Communications chemistry · 2024
    Article
  3. Article
  4. Article
  5. Article
  6. Transition Metal Catalyst Free Synthesis of Olefins from Organoboron Derivatives.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022
    Review
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Arif MusicDepartment Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, 81377, Munich, Germany.ORCID http://orcid.org/0000-0002-4786-1268
Andreas N BaumannDepartment Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, 81377, Munich, Germany.ORCID http://orcid.org/0000-0002-2811-1787
Florian BoserDepartment Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, 81377, Munich, Germany.
Nicolas MüllerDepartment Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, 81377, Munich, Germany.
Florian MatzQuantum Chemistry and Physical Chemistry Section, KU Leuven, Celestijnenlaan 200f, box 2404, 3001, Leuven, Belgium.
Thomas C JagauQuantum Chemistry and Physical Chemistry Section, KU Leuven, Celestijnenlaan 200f, box 2404, 3001, Leuven, Belgium.ORCID http://orcid.org/0000-0001-5919-424X
Dorian DidierDepartment Chemie, Ludwig-Maximilians-Universität, Butenandtstraße 5-13, 81377, Munich, Germany.ORCID http://orcid.org/0000-0002-6358-1485

Funding

Deutsche Forschungsgemeinschaft DI 2227/2-1Deutsche Forschungsgemeinschaft DI 2227/4-1Deutsche Forschungsgemeinschaft SFB749Erasmus+European Research Council 851766LMU ExcellenceVerband der Chemischen Industrie Liebig Fellowship
6 · The paper itself

Abstract

Readily accessible tetraorganoborate salts undergo selective coupling reactions under blue light irradiation in the presence of catalytic amounts of transition-metal-free acridinium photocatalysts to furnish unsymmetrical biaryls, heterobiaryls and arylated olefins. This represents an interesting conceptual approach to forge C-C bonds between aryl, heteroaryl and alkenyl groups under smooth photochemical conditions. Computational studies were conducted to investigate the mechanism of the transformation.

Indexed as

cross-couplingheterocouplingorganoboratesoxidationphotocatalysis

Identifiers

PMID33306228
PMCPMC7986674

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.