ArticleAngewandte Chemie (International ed. in English)2021
Modifying Woodward-Hoffmann Stereoselectivity Under Vibrational Strong Coupling.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 34 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
34 citing papers in PubMed.
- Toward Reliable Spectroscopic Analysis of Reaction Kinetics in Polaritonic Chemistry.Nanophotonics (Berlin, Germany) · 2026Article
- Reservoir Dynamics in Vibrational Polaritons Revealed by Detuning-Dependent Ultrafast Spectroscopy.The journal of physical chemistry letters · 2026Article
- Cluster Formation and Phase Transitions Induced by Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Topological classification of cycloadditions occurring on-surface and in the solid-state.Communications chemistry · 2025Article
- Woodward and Hoffmann on Secondary Orbital Interactions. How to Make a Fine Two-Course Meal from Leftovers.Chemical record (New York, N.Y.) · 2025Review
- The Diels-Alder Reaction as a Mechanistic Probe for Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- A Phenomenological Symmetry Rule for Chemical Reactivity Under Vibrational Strong Coupling.Angewandte Chemie (International ed. in English) · 2025Article
- A Complete Active Space Self-Consistent Field Approach for Molecules in QED Environments.Journal of chemical theory and computation · 2025Article
- Theoretical Insights into the Resonant Suppression Effect in Vibrational Polariton Chemistry.Journal of the American Chemical Society · 2025Article
- Converting Second-Order Saddle Points to Transition States: New Principles for the Design of 4π Photoswitches.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025Article
- Measuring Kinetics under Vibrational Strong Coupling: Testing for a Change in the Nucleophilicity of Water and Alcohols.Angewandte Chemie (International ed. in English) · 2024Article
- Analytical Evaluation of Ground State Gradients in Quantum Electrodynamics Coupled Cluster Theory.Journal of chemical theory and computation · 2024Article
- Microfluidics and Nanofluidics in Strong Light-Matter Coupling Systems.Nanomaterials (Basel, Switzerland) · 2024Review
- Theory of Magnetic Properties in Quantum Electrodynamics Environments: Application to Molecular Aromaticity.Journal of chemical theory and computation · 2024Article
- Do Molecular Geometries Change Under Vibrational Strong Coupling?The journal of physical chemistry letters · 2024Article
- Wide-Dynamic-Range Control of Quantum-Electrodynamic Electron Transfer Reactions in the Weak Coupling Regime.The journal of physical chemistry letters · 2024Article
- Exploring the impact of vibrational cavity coupling strength on ultrafast CN +Nanophotonics (Berlin, Germany) · 2024Article
- Consequences of Vibrational Strong Coupling on Supramolecular Polymerization of Porphyrins.Journal of the American Chemical Society · 2024Article
- Ultrafast Spectroscopy under Vibrational Strong Coupling in Diphenylphosphoryl Azide.The journal of physical chemistry. A · 2024Article
- Molecular Polaritons for Chemistry, Photonics and Quantum Technologies.Chemical reviews · 2024Review
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
9 authors.
Funding
Abstract
Vibrational strong coupling (VSC) has recently been shown to change the rate and chemoselectivity of ground-state chemical reactions via the formation of light-matter hybrid polaritonic states. However, the observation that vibrational-mode symmetry has a large influence on charge-transfer reactions under VSC suggests that symmetry considerations could be used to control other types of chemical selectivity through VSC. Here, we show that VSC influences the stereoselectivity of the thermal electrocyclic ring opening of a cyclobutene derivative, a reaction which follows the Woodward-Hoffmann rules. The direction of the change in stereoselectivity depends on the vibrational mode that is coupled, as do changes in rate and reaction thermodynamics. These results on pericyclic reactions confirm that symmetry plays a key role in chemistry under VSC.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.