ArticleNature chemistry2021
Charge transfer driven by ultrafast spin transition in a CoFe Prussian blue analogue.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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Who cites it
31 citing papers in PubMed.
- Achieving Ambient-Temperature Multiway Bistability via Electron-Transfer-Coupled Spin-State Switching in 2D Hexagonal Materials.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Ultrafast Formation of Jahn-Teller Polarons Revealed by State-Selective Excitation in Correlated Spinel CoJournal of the American Chemical Society · 2026Article
- Multiscale phase nucleation driven by photoinduced polarons in a volume-changing material.Nature materials · 2026Article
- Heavy Prussian Blue Analog with Magnetic Ordering above 400 K.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Convergent Evolution: Self-Assembly of Small Molecule, Polymeric, and Inorganic Contrast Agents toward Advanced MRI.Journal of the American Chemical Society · 2025Review
- Interfacial Co-Operativity Enables Ultrafast Charge Transfer Within the Co-Fe Prussian Blue Analogue|Zno Heterostructure.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Stimuli-Responsive Low-Frequency Terahertz Absorption ON-OFF Switchability in Spin-Crossover Material.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Stimuli-responsive Prussian blue analogues.Journal of materials chemistry. C · 2025Review
- Steering artificial photosynthesis via photoinduced conversion of monometallic to bimetallic sites in FeCo nitroprussides.Nature communications · 2025Article
- Cooperativity of Electron Transfer Coupled Spin Transitions in a Tetranuclear Fe/Co Prussian Blue Analogue Revealed by Ultrafast Spectroscopy.Angewandte Chemie (International ed. in English) · 2025Article
- Highlighting Charge Redistribution Phenomenon in Mn-Based Prussian Blue Analogues for Enhancing Redox Stability.ChemSusChem · 2025Article
- Ultrafast charge-transfer-induced spin transition in cobalt-tungstate molecular photomagnets.Nature communications · 2025Article
- Investigation into recent advanced strategies of reactive oxygen species-mediated therapy based on Prussian blue: Conceptualization and prospect.Bioactive materials · 2025Review
- Charge-transfer dynamics in S-scheme photocatalyst.Nature reviews. Chemistry · 2025Review
- Ultrafast Two-Color X-Ray Emission Spectroscopy Reveals Excited State Landscape in a Base Metal Dyad.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- High-Spin State of a Ferrocene Electron Donor Revealed by Optical and X-ray Transient Absorption Spectroscopy.Journal of the American Chemical Society · 2024Article
- The Liquid Jet Endstation for Hard X-ray Scattering and Spectroscopy at the Linac Coherent Light Source.Molecules (Basel, Switzerland) · 2024Article
- Tracking nuclear motion in single-molecule magnets using femtosecond X-ray absorption spectroscopy.Nature communications · 2024Article
- Optical Phenomena in Molecule-Based Magnetic Materials.Chemical reviews · 2024Review
- Ultrafast and persistent photoinduced phase transition at room temperature monitored by streaming powder diffraction.Nature communications · 2024Article
Corrections and comments
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Photoinduced charge-transfer is an important process in nature and technology and is responsible for the emergence of exotic functionalities, such as magnetic order for cyanide-bridged bimetallic coordination networks. Despite its broad interest and intensive developments in chemistry and material sciences, the atomic-scale description of the initial photoinduced process, which couples intermetallic charge-transfer and spin transition, has been debated for decades; it has been beyond reach due to its extreme speed. Here we study this process in a prototype cyanide-bridged CoFe system by femtosecond X-ray and optical absorption spectroscopies, enabling the disentanglement of ultrafast electronic and structural dynamics. Our results demonstrate that it is the spin transition that occurs first on the Co site within ~50 fs, and it is this that drives the subsequent Fe-to-Co charge-transfer within ~200 fs. This study represents a step towards understanding and controlling charge-transfer-based functions using light.
Identifiers
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Registered trials
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