ArticleNature chemistry2021
Interplay of vibrational wavepackets during an ultrafast electron transfer reaction.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Quantum Light Spectroscopy.ACS central science · 2026Review
- Direct Observation of Franck-Condon Stimulated Emission and Sub-20 fs Relaxation in Photoexcited Flavins.The journal of physical chemistry letters · 2026Article
- Vibronically assisted sub-cycle charge transfer at a non-fullerene acceptor heterojunction.Nature communications · 2026Article
- Delocalization versus Coherence under Vibrational and Environmental Disorder in Photoexcited Supramolecular Aggregates.Journal of the American Chemical Society · 2026Article
- Capturing coherent pseudorotation through conical intersection in photoionized benzene.Nature communications · 2025Article
- Quantum simulation of charge and exciton transfer in multi-mode models using engineered reservoirs.Nature communications · 2025Article
- Vibronic coupling-driven symmetry breaking and solvation in the photoexcited dynamics of quadrupolar dyes.Nature chemistry · 2025Article
- Vibronically Coherent Exciton Trapping in Monolayer WSACS nano · 2025Article
- Optical coherent quantum control of ultrafast protein electron transfer.Science advances · 2025Article
- A numerically exact description of ultrafast vibrational decoherence in vibration-coupled electron transfer.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Ultrafast Time-Domain Spectroscopy Reveals Coherent Vibronic Couplings upon Electronic Excitation in Crystalline Organic Thin Films.The journal of physical chemistry letters · 2024Article
- Stretching vibration driven adiabatic transfer kinetics for photoexcited hole transfer from semiconductor to adsorbate.Nature communications · 2024Article
- Transient-absorption spectroscopy of dendrimersChemical science · 2024Article
- Robust vibrational coherence protected by a core-shell structure in silver nanoclusters.Chemical science · 2024Article
- Article
- Directed ultrafast conformational changes accompany electron transfer in a photolyase as resolved by serial crystallography.Nature chemistry · 2024Article
- Two-Dimensional Electronic Spectroscopy Resolves Relative Excited-State Displacements.The journal of physical chemistry letters · 2024Article
- What is cooking in your kitchen: seeing "invisible" with time-resolved coherent anti-Stokes Raman spectroscopy.Analytical and bioanalytical chemistry · 2023Article
- The Marcus dimension: identifying the nuclear coordinate for electron transfer fromChemical science · 2023Article
- Modeling Excited-State Proton Transfer Using the Lindblad Equation: Quantification of Time-Resolved Spectroscopy with Mechanistic Insights.ACS physical chemistry Au · 2023Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Electron transfer reactions facilitate energy transduction and photoredox processes in biology and chemistry. Recent findings show that molecular vibrations can enable the dramatic acceleration of some electron transfer reactions, and control it by suppressing and enhancing reaction paths. Here, we report ultrafast spectroscopy experiments and quantum dynamics simulations that resolve how quantum vibrations participate in an electron transfer reaction. We observe ballistic electron transfer (~30 fs) along a reaction coordinate comprising high-frequency promoting vibrations. Along another vibrational coordinate, the system becomes impulsively out of equilibrium as a result of the electron transfer reaction. This leads to the generation (by the electron transfer reaction, not the laser pulse) of a new vibrational coherence along this second reaction coordinate in a mode associated with the reaction product. These results resolve a complex reaction trajectory composed of multiple vibrational coordinates that, like a sequence of ratchets, progressively diminish the recurrence of the reactant state.
Identifiers
33288893What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.