ArticleEntropy (Basel, Switzerland)2019
Ice-Crystal Nucleation in Water: Thermodynamic Driving Force and Surface Tension. Part I: Theoretical Foundation.
Article in Entropy (Basel, Switzerland), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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5 citing papers in PubMed.
- Self-Organisation of Prediction Models.Entropy (Basel, Switzerland) · 2023Review
- New Sensor to Measure the Microencapsulated Active Compounds Released in an Aqueous Liquid Media Based in Dielectric Properties in Radiofrequency Range.Sensors (Basel, Switzerland) · 2021Article
- Statistical Approach to Crystal Nucleation in Glass-Forming Liquids.Entropy (Basel, Switzerland) · 2021Article
- Analytical Determination of the Nucleation-Prone, Low-Density Fraction of Subcooled Water.Entropy (Basel, Switzerland) · 2020Article
- Entropy and the Tolman Parameter in Nucleation Theory.Entropy (Basel, Switzerland) · 2019Article
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Abstract
A recently developed thermodynamic theory for the determination of the driving force of crystallization and the crystal-melt surface tension is applied to the ice-water system employing the new Thermodynamic Equation of Seawater TEOS-10. The deviations of approximative formulations of the driving force and the surface tension from the exact reference properties are quantified, showing that the proposed simplifications are applicable for low to moderate undercooling and pressure differences to the respective equilibrium state of water. The TEOS-10-based predictions of the ice crystallization rate revealed pressure-induced deceleration of ice nucleation with an increasing pressure, and acceleration of ice nucleation by pressure decrease. This result is in, at least, qualitative agreement with laboratory experiments and computer simulations. Both the temperature and pressure dependencies of the ice-water surface tension were found to be in line with the le Chatelier-Braun principle, in that the surface tension decreases upon increasing degree of metastability of water (by decreasing temperature and pressure), which favors nucleation to move the system back to a stable state. The reason for this behavior is discussed. Finally, the Kauzmann temperature of the ice-water system was found to amount T K = 116 K , which is far below the temperature of homogeneous freezing. The Kauzmann pressure was found to amount to p K = - 212 MPa , suggesting favor of homogeneous freezing on exerting a negative pressure on the liquid. In terms of thermodynamic properties entering the theory, the reason for the negative Kauzmann pressure is the higher mass density of water in comparison to ice at the melting point.
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