ArticleNature chemistry2021
Competition between chiral solvents and chiral monomers in the helical bias of supramolecular polymers.
Article in Nature chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 41 papers.
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Who cites it
41 citing papers in PubMed.
- Pathway Complexity in Naphthalene Diimide Supramolecular Polymers: Interruption by an Aromatic Solvent.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Adaptive Cavity-Enabled Crystalline Chirality in Nanocarbon Cages.Angewandte Chemie (International ed. in English) · 2026Article
- Local Solvent Ordering Drives Supramolecular Chirality Inversion.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- How Crystal Size and Number Steer Asymmetric Crystallization.The journal of physical chemistry letters · 2026Article
- Ultrasound-Triggered Self-Assembly of Discrete Oligourethanes into Supramolecular Gels: Importance of Stereocenter Sequence.ACS macro letters · 2026Article
- Solvation Entropy as a Lever for Steering the Macroscopic Properties of a Functional Supramolecular Helical Polymer.Angewandte Chemie (International ed. in English) · 2026Article
- A hydroxyl group dictates handedness, pitch, and mechanics in a crystalline covalent helical polymer.Science advances · 2025Article
- Spatial Control of Chiral Self-Assembly and Lithographic Applications in Liquid Crystal Polymer Network.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Crafting defects in two-dimensional organic platelets via seeded coassembly enables emergent molecular recognition.Nature communications · 2025Article
- Supramolecular chiral inversion and regulation of phenylalanine-based organogels in low-polarity achiral solvents.Communications chemistry · 2025Article
- Amplification of Asymmetry via Structural Transitions in Supramolecular Polymer-Surfactant Coassemblies.Journal of the American Chemical Society · 2025Article
- Solvent-Free Supramolecular Polymerization for Feather-Like Nanostructured Chiral Fluorescent Polyurethanes with Multimodal Chiroptical Stimuli Responsiveness.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization.Nature chemistry · 2025Review
- Supramolecular rosette intermediated homochiral double helix.Nature communications · 2025Article
- Amplifying and Reversing the Chiral Bias in Asymmetric Photo-Polymerization Reaction.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Chiral Induction of a Tetrakis(porphyrin) in Various Chiral Solvents.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Article
- Electric Fields in Polymeric Systems.Chemical reviews · 2024Review
- Pathway-directed recyclable chirality inversion of coordinated supramolecular polymers.Nature communications · 2024Article
- Recent advances in shape memory scaffolds and regenerative outcomes.Biomedical engineering letters · 2024Review
- Well-Defined Synthetic Copolymers with Pendant Aldehydes Form Biocompatible Strain-Stiffening Hydrogels and Enable Competitive Ligand Displacement.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Solute-solvent interactions are key for the assembly and proper functioning of biomacromolecules and play important roles in many fields of organic and polymer chemistry. Despite numerous reports describing the effects of (chiral) solvents on helical conformations of (supramolecular) polymers, the combination of chiral solvents and chiral monomers is unexplored. Here we report diastereomeric differences in the supramolecular polymerization of enantiomers of chiral triphenylene-2,6,10-tricarboxamides in chiral chlorinated solvents. Competition between the preferences induced by the stereocentres of the assembled monomers and those present in the solvent molecules results in unforeseen temperature-dependent solvation effects. By combining experiments and mathematical modelling, we show that the observed differences between enantiomers originate from the combined additive entropic effects of stereocentres present in the monomer and in the solvent. Remarkably, copolymerizations show that the chiral solvent can bias the copolymer helicity and thereby overrule the helical preference of the monomers. Our results highlight the importance of cumulative solvation effects in supramolecular polymerizations.
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Registered trials
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