ArticleChemical science2020
Pnictogen-bonding catalysis: brevetoxin-type polyether cyclizations.
Article in Chemical science, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- σ-Hole Engineering Enables Selective Supramolecular Isomer Formation in Sb(III) Hosts.Inorganic chemistry · 2026Article
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bridging Lewis acidic antimony centers with electron-withdrawing carborane cages.Chemical science · 2026Article
- Pnictogen-bonding-crosslinked polymer networks: constructing self-healing materials.Chemical science · 2026Article
- Article
- Flash Communication: Properties and Applications of a Pentavalent Bromoantimony Lewis Acid.Organometallics · 2026Article
- Pnictogen-Bonding Catalysis: Copolymerization of COACS catalysis · 2025Article
- Medical and Nonmedical Applications of Synthetic Transmembrane Anion Transporters.Chemical reviews · 2025Review
- Lewis Acidity of the SbClAngewandte Chemie (International ed. in English) · 2025Article
- Pnictogen bonding enabled photosynthesis of chiral selenium-containing pyridines from pyridylphosphonium salts.Fundamental research · 2025Article
- Applications of Antimony in Catalysis.ACS organic & inorganic Au · 2025Review
- Steric Selection of Anion Binding Sites by Organoantimony(V) Pnictogen Bond Donors: An Experimental and Computational Study.Inorganic chemistry · 2024Article
- Poly-pnictogen bonding: trapping halide ions by a tetradentate antimony(iii) Lewis acid.Chemical science · 2023Article
- Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids.Journal of the American Chemical Society · 2023Review
- Are ArOrganometallics · 2023Article
- A Quantum-chemical Analysis on the Lewis Acidity of Diarylhalonium Ions.Chemphyschem : a European journal of chemical physics and physical chemistry · 2023Article
- Anion-π catalysis on carbon allotropes.Beilstein journal of organic chemistry · 2023Review
- Anion Recognition with Antimony(III) and Bismuth(III) Triaryl-Based Pnictogen Bonding Receptors.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Decoded fingerprints of hyperresponsive, expanding product space: polyether cascade cyclizations as tools to elucidate supramolecular catalysis.Chemical science · 2022Article
- The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor.Molecules (Basel, Switzerland) · 2022Review
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Pnictogen-bond donors are attractive for use in catalysis because of deep σ holes, high multivalency, rich hypervalency, and chiral binding pockets. We here report natural product inspired epoxide-opening polyether cyclizations catalyzed by fluoroarylated Sb(v) > Sb(iii) > Bi > Sn > Ge. The distinctive characteristic found for pnictogen-bonding catalysis is the breaking of the Baldwin rules, that is selective
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