ArticleMikrochimica acta2020
Mesoporous MIP-capped luminescent MOF as specific and sensitive analytical probe: application for chlorpyrifos.
Article in Mikrochimica acta, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- The influence of HKUST-1 and MOF-76 hand grinding/mechanical activation on stability, particle size, textural properties and carbon dioxide sorption.Scientific reports · 2024Article
- [Recent advances in the applications of metal-organic frameworks-based molecularly imprinted materials].Se pu = Chinese journal of chromatography · 2023Article
- Article
- Application of a needle trap device packed with a MIP@MOF nano-composite for efficient sampling and determination of airborne diazinon pesticide.RSC advances · 2022Article
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4 authors.
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Abstract
Specific recognition of organophosphate pesticides (OPs) is a significant challenge for analytical researchers. Herein, surface imprinted terbium-based luminescent metal-organic framework (MOF-76) are presented as a highly specific probe for the measurement of chlorpyrifos (CP). A mesoporous molecular imprinted polymer (mMIP) layer was generated on the surface of nano-sized MOF-76 using CP, as template. The resulting mMIP-capped MOF-76 (mMIP@MOF-76) contained specific sites for adsorption of CP molecules, guaranteeing the selectivity of the designed probe. The high porosity of rod-shape MOF-76, as well as the mesoporous structure of the MIP layer improved the diffusion process and caused the high sensitivity of the probe. The detection process is based on the remarkable quenching effect of CP on the fluorescence emission of mMIP@MOF-76. Plotting the CP concentration against the fluorescence intensity (λ
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