Evidence map›Paper›PMID 33236239›Full record

ArticleMikrochimica acta2020

Mesoporous MIP-capped luminescent MOF as specific and sensitive analytical probe: application for chlorpyrifos.

Habibeh Eskandari, Maliheh Amirzehni, Javad Hassanzadeh, Behrouz Vahid

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Article in Mikrochimica acta, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

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4citing papers in PubMed
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4 citing papers in PubMed.

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5 · Who and what money

Authors and funding

4 authors.

Habibeh EskandariDepartment of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran.
Maliheh AmirzehniDepartment of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran.
Javad HassanzadehDepartment of Chemistry, College of Science, Sultan Qaboos University, Box 36, Al-Khod 123, Muscat, Oman. javadhassanzadeh63@gmail.com.ORCID 0000-0001-8316-1982
Behrouz VahidDepartment of Chemical Engineering, Tabriz Branch, Islamic Azad University, Tabriz, Iran. behrouz_vahid@iaut.ac.ir.ORCID 0000-0003-2767-1915

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Specific recognition of organophosphate pesticides (OPs) is a significant challenge for analytical researchers. Herein, surface imprinted terbium-based luminescent metal-organic framework (MOF-76) are presented as a highly specific probe for the measurement of chlorpyrifos (CP). A mesoporous molecular imprinted polymer (mMIP) layer was generated on the surface of nano-sized MOF-76 using CP, as template. The resulting mMIP-capped MOF-76 (mMIP@MOF-76) contained specific sites for adsorption of CP molecules, guaranteeing the selectivity of the designed probe. The high porosity of rod-shape MOF-76, as well as the mesoporous structure of the MIP layer improved the diffusion process and caused the high sensitivity of the probe. The detection process is based on the remarkable quenching effect of CP on the fluorescence emission of mMIP@MOF-76. Plotting the CP concentration against the fluorescence intensity (λ

Indexed as

Molecular ImprintingChlorpyrifosDrinking WaterFruit and Vegetable JuicesLimit of DetectionMetal-Organic FrameworksPesticidesPolymersPorosityReproducibility of ResultsSpectrometry, FluorescenceTerbiumChlorpyrifosDrinking WaterMetal-Organic FrameworksPesticidesPolymersTerbiumChlorpyrifosFluorescence determinationMesoporous MOFNanosensorSurface imprintingTerbium metal-organic framework

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