ArticleJournal of the American Chemical Society2020
Electroreductive Carbofunctionalization of Alkenes with Alkyl Bromides via a Radical-Polar Crossover Mechanism.
Article in Journal of the American Chemical Society, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
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Who cites it
47 citing papers in PubMed.
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- Photocatalytic reductive carboxylation of unactivated hydrazones with CONature communications · 2026Article
- Recent Advances in the High-Value Conversion of Alkenes Induced by Electrochemistry.Molecules (Basel, Switzerland) · 2026Review
- Catalyst-Free Electro-photochemical Hydroalkylation ofJACS Au · 2026Article
- Electrochemical selective hydrocarboxylation of acrylamides with carbon dioxide for precise control of α- and β-carboxylation.Communications chemistry · 2025Article
- Markovnikov-Selective Electrocatalytic Hydroalkylation Enabled by Metal-Ligand Cooperative Storage of H-Atom Equivalents.ACS catalysis · 2025Article
- Photocatalytic Generation of a Ground-State Electron Donor Through Water Activation.Angewandte Chemie (International ed. in English) · 2025Article
- Facile, general allylation of unactivated alkyl halidesChemical science · 2025Article
- Photocatalytic 1,3-difluoroalkylcarboxylation of alkenes by triple kinetic-controlled radical self-ordering.Chemical science · 2025Article
- Article
- Electrochemical Synergistic Ni/Co-Catalyzed Carbonylative Cross-Electrophile Coupling of Aryl and Alkyl Halides with CO.JACS Au · 2025Article
- A General Hydrotrifluoromethylation of Unactivated Olefins Enabled by Voltage-Gated Electrosynthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Alkene Carboxy-Alkylation via COJournal of the American Chemical Society · 2024Article
- Paired Electrolysis Enables Reductive Heck Coupling of Unactivated (Hetero)Aryl Halides and Alkenes.Angewandte Chemie (International ed. in English) · 2024Article
- Electrochemical Glycosylation via Halogen-Atom-Transfer forACS catalysis · 2024Article
- Zinc Promoted Cross-Electrophile Sulfonylation to Access Alkyl-Alkyl Sulfones.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Electroreductive deuteroarylation of alkenes enabled by an organo-mediator.Chemical science · 2024Article
- Hydroalkylation of styrenes enabled by boryl radical mediated halogen atom transfer.Chemical science · 2024Article
- A guide to troubleshooting metal sacrificial anodes for organic electrosynthesis.Chemical science · 2024Review
- Visible-light-driven alkene dicarboxylation with formate and COChemical science · 2024Article
Corrections and comments
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Authors and funding
2 authors.
Funding
Abstract
Electrochemistry grants direct access to reactive intermediates (radicals and ions) in a controlled fashion toward selective organic transformations. This feature has been demonstrated in a variety of alkene functionalization reactions, most of which proceed via an anodic oxidation pathway. In this report, we further expand the scope of electrochemistry to the reductive functionalization of alkenes. In particular, the strategic choice of reagents and reaction conditions enabled a radical-polar crossover pathway wherein two distinct electrophiles can be added across an alkene in a highly chemo- and regioselective fashion. Specifically, we used this strategy in the intermolecular carboformylation,
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