ArticleNanoscale2020
Microporous silica membranes promote plasmonic nanoparticle stability for SERS detection of uranyl.
Article in Nanoscale, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
2 citing papers in PubMed.
- Threonine Phosphorylation of an Electrochemical Peptide-Based Sensor to Achieve Improved Uranyl Ion Binding Affinity.Biosensors · 2022Article
- Surface-enhanced Raman spectroscopy for drug discovery: peptide-RNA binding.Analytical and bioanalytical chemistry · 2022Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Silica membrane stabilized gold coated silver (Ag@Au) (i.e., internally etched silica coated Ag@Au (IE Ag@Au@SiO2)) nanoparticles promote surface-enhanced Raman scattering (SERS) activity and detection of uranium(vi) oxide (uranyl) under harsh solution phase conditions including at pH 3-7, with ionic strengths up to 150 mM, and temperatures up to 37 °C for at least 10 hours. These materials overcome traditional solution-phase plasmonic nanomaterial limitations including signal variability and/or degradation arising from nanoparticle aggregation, dissolution, and/or surface chemistry changes. Quantitative uranyl detection occurs via coordination to 3-mercaptopropionate (MPA), a result confirmed through changes in correlated SERS intensities for uranyl and COOH/COO- vibrational modes. Quantification is demonstrated down to 110 nM, a concentration below toxic levels. As pH varies from 3 to 7, the plasmonic properties of the nanoparticles are unchanged, and the uranyl signal depends on both the protonation state of MPA as well as uranyl solubility. High ionic strengths (up to 150 mM) and incubation at 37 °C for at least 10 hours do not impact the SERS activity of uranyl even though slight silica dissolution is observed during thermal treatment. All in all, microporous silica membranes effectively protect the nanoparticles against variations in solution conditions thus illustrating robust tunability for uranyl detection using SERS.
Identifiers
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Registered trials
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