Evidence map›Paper›PMID 33213037›Full record

ReviewMolecules (Basel, Switzerland)2020

Diels-Alder Cycloaddition to the Bay Region of Perylene and Its Derivatives as an Attractive Strategy for PAH Core Expansion: Theoretical and Practical Aspects.

Aneta Kurpanik, Marek Matussek, Piotr Lodowski, Grażyna Szafraniec-Gorol, Michał Krompiec, Stanisław Krompiec

Abstract readReview
In one paragraph

Review in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Effect of Excitation Wavelength in Single-Molecule Photochemistry of Terrylene.Chemphyschem : a European journal of chemical physics and physical chemistry · 2025
    Article
  2. Article
  3. Article
  4. Article
  5. Diels-Alder Cycloaddition with CO, COMaterials (Basel, Switzerland) · 2021
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Aneta KurpanikInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, 40-007 Katowice, Poland.
Marek MatussekInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, 40-007 Katowice, Poland.
Piotr LodowskiInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, 40-007 Katowice, Poland.
Grażyna Szafraniec-GorolInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, 40-007 Katowice, Poland.ORCID 0000-0002-0741-4420
Michał KrompiecMerck Chemicals Ltd., 1 Venture Road, Southampton SO16 7NP, UK.
Stanisław KrompiecInstitute of Chemistry, Faculty of Science and Technology, University of Silesia, Bankowa 14, 40-007 Katowice, Poland.ORCID 0000-0003-3516-4235

Funding

Narodowe Centrum Nauki 2016/21/B/ST5/00805Narodowe Centrum Nauki 2019/33/B/ST4/00962Narodowe Centrum Nauki 2019/33/N/ST4/00817Narodowe Centrum Nauki 2019/35/B/ST4/00115
6 · The paper itself

Abstract

PAHs (polycyclic aromatics hydrocarbons), the compound group that contains perylene and its derivatives, including functionalized ones, have attracted a great deal of interest in many fields of science and modern technology. This review presents all of the research devoted to modifications of PAHs that are realized via the Diels-Alder (DA) cycloaddition of various dienophiles to the bay regions of PAHs, leading to the π-extension of the starting molecule. This type of annulative π-extension (APEX) strategy has emerged as a powerful and efficient synthetic method for the construction of polycyclic aromatic hydrocarbons and their functionalized derivatives, nanographenes, and π-extended fused heteroarenes. Then, [4 + 2] cycloadditions of ethylenic dienophiles, -N=N-, i.e., diazo-dienophiles and acetylenic dienophiles, are presented. This subject is discussed from the organic synthesis point of view but supported by theoretical calculations. The possible applications of DA cycloaddition to PAH bay regions in various science and technology areas, and the prospects for the development of this synthetic method, are also discussed.

Indexed as

Cycloaddition ReactionEstersPerylenePolycyclic Aromatic HydrocarbonsThermodynamicsEstersPerylenePolycyclic Aromatic HydrocarbonsAPEXbay regionDiels–Alder cycloadditionnanographenesperylene

Identifiers

PMID33213037
PMCPMC7698498

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.