ReviewChemistry (Weinheim an der Bergstrasse, Germany)2021
As Nice as π: Aromatic Reactions Activated by π-Coordination to Transition Metals.
Review in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Transient π-coordination enables nucleophilic borylation of simple arenes.Chemical science · 2026Article
- Arene activation via π-bond localization: concepts and opportunities.Beilstein journal of organic chemistry · 2026Review
- Formation of Heteropolycyclic Frameworks via the Dearomatization of a Dihapto-Coordinated Anisole.Organometallics · 2025Article
- Ruthenium-MediatedJournal of the American Chemical Society · 2025Article
- Extensive Studies on the Synthesis and Characterization of π-Arene Chromium Complexes and Their Performance in SChemistry, an Asian journal · 2025Article
- Isolation of a planar π-aromatic BiNature chemistry · 2025Article
- Photoredox-Catalyzed Nucleophilic Aromatic Substitution of Halophenols with Azoles via Oligomeric Phenylene Oxide Radicals.Journal of the American Chemical Society · 2025Article
- Decarboxylative Cross-Coupling Enabled by Fe and Ni Metallaphotoredox Catalysis.Journal of the American Chemical Society · 2024Article
- Ruthenium Phenoxo Complexes: An Isolobal Ligand to Cp with Improved Properties.Journal of the American Chemical Society · 2024Article
- Noncovalent interaction with a spirobipyridine ligand enables efficient iridium-catalyzed C-H activation.Nature communications · 2024Article
- Pd-catalyzed allylative dearomatisation using Grignard reagents.Chemical communications (Cambridge, England) · 2021Article
- As Nice as π: Aromatic Reactions Activated by π-Coordination to Transition Metals.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Review
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
π-Coordination of aromatic molecules to metals dramatically alters their reactivity. For example, coordinated carbons become more electrophilic and C-H bonds of coordinated rings become more acidic. For many years, this change in reactivity has been used to trigger reactions that would not take place for uncoordinated arenes, however, there has been a recent resurgence in use of this technique, in part due to the development of catalytic reactions in which π-coordination is transient. In this Minireview, we describe the key reaction chemistry of arenes coordinated to a range of transition metals, including stereoselective reactions and industrially relevant syntheses. We also summarise outstanding examples of catalytic processes. Finally, we give perspectives on the future direction of the field, with respect to both reactions that are stoichiometric in activating metals and those employing catalytic metal.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.