ArticleChemistry (Weinheim an der Bergstrasse, Germany)2021
Base-Free Pd-Catalyzed C-Cl Borylation of Fluorinated Aryl Chlorides.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Applications of Transition Metal-CatalyzedChemical reviews · 2024Review
- Visible-light-induced selective defluoroalkylations of polyfluoroarenes with alcohols.Chemical science · 2023Article
- Transition Metal Catalyst-Free, Base-Promoted 1,2-Additions of Polyfluorophenylboronates to Aldehydes and Ketones.Angewandte Chemie (International ed. in English) · 2021Article
- Base-Free Pd-Catalyzed C-Cl Borylation of Fluorinated Aryl Chlorides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
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Authors and funding
5 authors.
Funding
Abstract
Catalytic C-X borylation of aryl halides containing two ortho-fluorines has been found to be challenging, as most previous methods require stoichiometric amounts of base and the polyfluorinated aryl boronates suffer from protodeboronation, which is accelerated by ortho-fluorine substituents. Herein, we report that a combination of Pd(dba)
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