Evidence map›Paper›PMID 33195918›Full record

ArticleACS omega2020

Probing Electronic Communication and Excited-State Dynamics in the Unprecedented Ferrocene-Containing Zinc MB-DIPY.

Yuriy V Zatsikha, Liliya I Shamova, Jacob W Schaffner, Andrew T Healy, Tanner S Blesener, Gabriel Cohen, Brandon Wozniak, David A Blank, Victor N Nemykin

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS omega, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Yuriy V ZatsikhaDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.
Liliya I ShamovaDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.
Jacob W SchaffnerDepartment of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Andrew T HealyDepartment of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Tanner S BlesenerDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.
Gabriel CohenDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.
Brandon WozniakDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.
David A BlankDepartment of Chemistry, University of Minnesota, 207 Pleasant St. SE, Minneapolis, Minnesota 55455, United States.
Victor N NemykinDepartment of Chemistry, University of Manitoba, Winnipeg, Manitoba R3T 2N2, Canada.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The electronic communication between two ferrocene groups in the electron-deficient expanded aza-BODIPY analogue of zinc manitoba-dipyrromethene (MB-DIPY) was probed by spectroscopic, electrochemical, spectroelectrochemical, and theoretical methods. The excited-state dynamics involved sub-ps formation of the charge-separated state in the organometallic zinc MB-DIPYs, followed by recovery of the ground state via charge recombination in 12 ps. The excited-state behavior was contrasted with that observed in the parent complex that lacked the ferrocene electron donors and has a much longer excited-state lifetime (670 ps for the singlet state). Much longer decay times observed for the parent complex without ferrocene confirm that the main quenching mechanism in the ferrocene-containing

Identifiers

PMID33195918
PMCPMC7658947

What OpenQuestion holds

Textmetadata
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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.