Synthesis of an Alternated Heterobimetallic Supramolecular Polymer Based on Ru(II) and Fe(II).

Manas Kumar Bera, Yoshikazu Ninomiya, Masayoshi Higuchi

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

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0cells of the map it votes in

1citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

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Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach.Inorganic chemistry · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Manas Kumar BeraElectronic Functional Macromolecules Group, Research Center for Functional Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.ORCID 0000-0003-4784-9530

Yoshikazu NinomiyaElectronic Functional Macromolecules Group, Research Center for Functional Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.

Masayoshi HiguchiElectronic Functional Macromolecules Group, Research Center for Functional Materials, National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.ORCID 0000-0001-9877-1134

Funding

Core Research for Evolutional Science and Technology JPMJCR1533

6 · The paper itself

Abstract

A heterobimetallic supramolecular polymer (polyRuFe) with alternately complexed Ru(II) and Fe(II) is prepared following a stepwise synthetic route through harnessing first the strongly binding metal ion Ru(II) and then the weakly binding metal ion Fe(II). A high yield of product is achieved in each step. The heterometal ions are incorporated into the polymer chain in identical coordination environments formed by two 2,2':6',2″-terpyridine moieties. Characterization is accomplished by NMR spectroscopy, MALDI-TOF mass spectrometry, UV-Vis spectroscopy, and cyclic voltammetry. PolyRuFe shows a wide optical window (

Indexed as

Chemistry Techniques, SyntheticFerrous CompoundsIonsIronLigandsMagnetic Resonance SpectroscopyMetalsModels, MolecularMolecular ConformationMolecular StructureOxidation-ReductionPolymersPyridinesRutheniumSpectrometry, Mass, Matrix-Assisted Laser Desorption-IonizationSpectrophotometry, UltravioletFerrous CompoundsIonsIronLigandsMetalsPolymersPyridinesRutheniumbimetallicheterometallic supramolecular polymerironrutheniumterpyridine

Identifiers

PMID33187379

DOI10.3390/molecules25225261

PMCPMC7698060

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