ArticleScience advances2020
Light-driven, heterogeneous organocatalysts for C-C bond formation toward valuable perfluoroalkylated intermediates.
Article in Science advances, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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The trial behind it
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Who cites it
22 citing papers in PubMed.
- Light-driven ammonia electrooxidation via carbon nitride-ruthenium molecular interfaces.Beilstein journal of nanotechnology · 2026Article
- Toward Reliable and Reproducible Research in Organic Photocatalysis by Carbon Nitride.ACS catalysis · 2025Review
- General method for carbon-heteroatom cross-coupling reactions via semiheterogeneous red-light metallaphotocatalysis.Nature communications · 2025Article
- Photocatalytic C(spNature communications · 2025Article
- Nile Red-Based Covalent Organic Framework as a Photocatalyst for C-H Bond Functionalization.ACS catalysis · 2025Article
- What Is to Be Expected from Heterogeneous Catalysis in the Pipeline to Circular Economy?ChemSusChem · 2025Review
- Article
- Diastereoselective dearomatization of indoles via photocatalytic hydroboration on hydramine-functionalized carbon nitride.Nature communications · 2024Article
- Heterogeneous Organocatalysts for Light-Driven Reactions in Continuous Flow.Molecules (Basel, Switzerland) · 2024Review
- Polylactic acid-based dressing with oxygen generation and enzyme-like activity for accelerating both light-driven biofilm elimination and wound healing.Burns & trauma · 2024Article
- Carbon Vacancies Steer the Activity in Dual Ni Carbon Nitride Photocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Modulable Photocatalyzed Strategies for the Synthesis of α-Organic letters · 2023Article
- Humin Formation on SBA-15-pr-SOACS applied materials & interfaces · 2023Article
- Morphology and Light-Dependent Spatial Distribution of Spin Defects in Carbon Nitride.Angewandte Chemie (International ed. in English) · 2022Article
- Edge modification facilitated heterogenization and exfoliation of two-dimensional nanomaterials for cancer catalytic therapy.Science advances · 2022Article
- The Nickel Age in Synthetic Dual Photocatalysis: A Bright Trip Toward Materials Science.ChemSusChem · 2022Review
- Radical defects modulate the photocatalytic response in 2D-graphitic carbon nitride.Chemical science · 2022Article
- Photoredox Cross-Dehydrogenative Coupling ofThe Journal of organic chemistry · 2022Article
- An Integrated Carbon Nitride-Nickel Photocatalyst for the Amination of Aryl Halides Using Sodium Azide.Angewandte Chemie (International ed. in English) · 2022Article
- Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions.Angewandte Chemie (International ed. in English) · 2022Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The favorable exploitation of carbon nitride (CN) materials in photocatalysis for organic synthesis requires the appropriate fine-tuning of the CN structure. Here, we present a deep investigation of the structure/activity relationship of CN in the photocatalytic perfluoroalkylation of organic compounds. Four types of CN bearing subtle structural differences were studied via conventional characterization techniques and innovative nuclear magnetic resonance (NMR) experiments, correlating the different structures with the fundamental mechanistic nexus and especially highlighting the importance of the halogen bond strength between the reagent and the catalyst surface. The optimum catalyst exhibited an excellent performance, with a very wide reaction scope, and could prominently trigger the model reaction using natural sunlight. The work lays a platform for establishing a new approach in the development of heterogeneous photocatalysts for organic synthesis related to medical, agricultural, and material chemistry.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.