Evidence map›Paper›PMID 33163326›Full record

ArticleChemistryOpen2020

Donor-Stabilized Monocarba-Bridged Bis(cyclopentadienyl)alanes.

Wasim Haider, Volker Huch, Bernd Morgenstern, André Schäfer

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemistryOpen, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Wasim HaiderFaculty of Natural Sciences and Technology, Department of Chemistry, Saarland University, 66123, Saarbrücken, Saarland, Federal Republic of Germany.
Volker HuchFaculty of Natural Sciences and Technology, Department of Chemistry, Saarland University, 66123, Saarbrücken, Saarland, Federal Republic of Germany.
Bernd MorgensternFaculty of Natural Sciences and Technology, Department of Chemistry, Saarland University, 66123, Saarbrücken, Saarland, Federal Republic of Germany.
André SchäferFaculty of Natural Sciences and Technology, Department of Chemistry, Saarland University, 66123, Saarbrücken, Saarland, Federal Republic of Germany.ORCID http://orcid.org/0000-0002-5969-6618

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Five monocarba-bridged bis(cyclopentadienyl)aluminum halide NHC and thione complexes and one monocarba-bridged bis(cyclopentadienyl)phosphanylalane NHC complex are reported. The former were synthesized by transmetalation of a C[1]magnesocenophane with the corresponding aluminum(III) chloride and aluminum(III) bromide donor adducts. The phosphanylalane complex was obtained by a subsequent functionalization of the corresponding bromoalane with lithium diphenylphosphide. All complexes were characterized in solution by multinuclear NMR spectroscopy and in the solid state by single crystal X-ray diffraction. Bonding energies of the NHC and thione ligands to the aluminum centres were estimated by DFT calculations.

Indexed as

aluminumcyclopentadienylalanesmetallocenophanesNHCsphosphanylalanes

Identifiers

PMID33163326
PMCPMC7607447

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.