ArticleAngewandte Chemie (International ed. in English)2021
Pathway and Length Control of Supramolecular Polymers in Aqueous Media via a Hydrogen Bonding Lock.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
18 citing papers in PubMed, 134 citations in OpenAlex.
- Pathway Complexity in Naphthalene Diimide Supramolecular Polymers: Interruption by an Aromatic Solvent.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Cosolvent-Modulated Supramolecular Chirality Unveils Pronounced Piezoelectric Response in Peptide-Based Nanomaterials.Angewandte Chemie (International ed. in English) · 2026Article
- Self-Assembled (Aza)BODIPY Dyes for Biomedical in Vivo Imaging.Angewandte Chemie (International ed. in English) · 2026Review
- Self-assembling nanocomposites for smart drug delivery: towards personalized and stimuli-responsive therapeutics.RSC advances · 2026Review
- Elucidating the Boundary of Intercalation vs Sequestration in Supramolecular Polymers by Retrosynthetic Design Toward the Construction of Complex Supramolecular Systems.Angewandte Chemie (International ed. in English) · 2025Article
- A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization.Nature communications · 2024Article
- Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(ii) terpyridine complex through competitive complex formation.Chemical science · 2024Article
- Water-Assisted Programmable Assembly of Flexible and Self-Standing Janus Membranes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Investigation of Weak Noncovalent Interactions Directed by the Amino Substituent of Pyrido- and Pyrimido-[1,2-ACS omega · 2023Article
- Investigating the Impact of Hydrophobic Polymer Segments on the Self-Assembly Behavior of Supramolecular Cyclic Peptide Systems via Asymmetric-Flow Field Flow Fractionation.Macromolecules · 2023Article
- Stacked or Folded? Impact of Chelate Cooperativity on the Self-Assembly Pathway to Helical Nanotubes from Dinucleobase Monomers.Journal of the American Chemical Society · 2023Article
- Acylhydrazone-based supramolecular assemblies undergoing a converse sol-to-gel transition onChemical science · 2022Article
- Article
- Anti-cooperative Self-Assembly with Maintained Emission Regulated by Conformational and Steric Effects.Angewandte Chemie (International ed. in English) · 2022Article
- Transient chirality inversion during racemization of a helical cobalt(III) complex.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- Globular Aggregates Stemming from the Self-Assembly of an AmphiphilicNanomaterials (Basel, Switzerland) · 2021Article
- Living supramolecular polymerization of fluorinated cyclohexanes.Nature communications · 2021Article
- Pathway and Length Control of Supramolecular Polymers in Aqueous Media via a Hydrogen Bonding Lock.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
Abstract
Programming the organization of π-conjugated systems into nanostructures of defined dimensions is a requirement for the preparation of functional materials. Herein, we have achieved high-precision control over the self-assembly pathways and fiber length of an amphiphilic BODIPY dye in aqueous media by exploiting a programmable hydrogen bonding lock. The presence of a (2-hydroxyethyl)amide group in the target BODIPY enables different types of intra- vs. intermolecular hydrogen bonding, leading to a competition between kinetically controlled discoidal H-type aggregates and thermodynamically controlled 1D J-type fibers in water. The high stability of the kinetic state, which is dominated by the hydrophobic effect, is reflected in the slow transformation to the thermodynamic product (several weeks at room temperature). However, this lag time can be suppressed by the addition of seeds from the thermodynamic species, enabling us to obtain supramolecular polymers of tuneable length in water for multiple cycles.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.