ArticleAngewandte Chemie (International ed. in English)2021
Theoretical, Solid-State, and Solution Quantification of the Hydrogen Bond-Enhanced Halogen Bond.
Article in Angewandte Chemie (International ed. in English), 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
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Who cites it
17 citing papers in PubMed.
- Cocrystals of 1,2-Diiodotetrafluorobenzene with Pyridine Derivatives: Pyridine Nitrogen as a Bifurcated Acceptor with Ortho-Diiodo Halogen Bond Donors.Crystal growth & design · 2026Article
- Asymmetric Mannich reaction of aromatic imines with malonates in the presence of multifunctional catalysts.Beilstein journal of organic chemistry · 2026Article
- The Next Frontier in the Study of Noncovalent Bonding: Transition Metals.Molecules (Basel, Switzerland) · 2025Article
- The nature of halogen bonding: insights from interacting quantum atoms and source function studies.IUCrJ · 2025Article
- From Polyester Plastics to Diverse Monomers via Low-Energy Upcycling.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Combination of Hydrogen and Halogen Bonds in the Crystal Structures of 5-Halogeno-1Molecules (Basel, Switzerland) · 2024Article
- The interplay between hydrogen and halogen bonding: substituent effects and their role in the hydrogen bond enhanced halogen bond.Chemical science · 2023Article
- Keggin-Type Anions as Halogen Bond Acceptors.Crystal growth & design · 2023Article
- ηChemistry, an Asian journal · 2023Article
- Anti-Hofmeister Anion Selectivity via a Mechanical Bond Effect in Neutral Halogen-Bonding [2]Rotaxanes.Angewandte Chemie (International ed. in English) · 2022Article
- Isolation and crystal and molecular structures of [(CActa crystallographica. Section C, Structural chemistry · 2022Article
- Pushing the limits of the hydrogen bond enhanced halogen bond-the case of the C-H hydrogen bond.Chemical science · 2022Article
- Halogen bonding organocatalysis enhanced through intramolecular hydrogen bonds.Chemical communications (Cambridge, England) · 2022Article
- Evaluation of Halogenopyridinium Cations as Halogen Bond Donors.Crystal growth & design · 2021Article
- Are bis(pyridine)iodine(I) complexes applicable for asymmetric halogenation?Organic & biomolecular chemistry · 2021Article
- Enantioselective Michael addition to vinyl phosphonatesChemical science · 2021Article
- Nature of the Hydrogen Bond Enhanced Halogen Bond.Molecules (Basel, Switzerland) · 2021Article
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Authors and funding
5 authors.
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Abstract
Proximal noncovalent forces are commonplace in natural systems and understanding the consequences of their juxtaposition is critical. This paper experimentally quantifies for the first time a Hydrogen Bond-Enhanced Halogen Bond (HBeXB) without the complexities of protein structure or preorganization. An HBeXB is a halogen bond that has been strengthened when the halogen donor simultaneously accepts a hydrogen bond. Our theoretical studies suggest that electron-rich halogen bond donors are strengthened most by an adjacent hydrogen bond. Furthermore, stronger hydrogen bond donors enhance the halogen bond the most. X-ray crystal structures of halide complexes (X
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